Coordination Compounds - Result Question 9

####11. The complex, $[Pt(Py)(NH_3) BrCl]$ will have how many geometrical isomers?

(a) 3

(b) 4

(c) 0

(d) 2

[2011]

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Solution:

  1. (a) Complexes of the type $M _{ABCD}$ may exist in three isomeric forms.

$ [Cr(H_2 O)_4 Cl_2] NO_3 $

(I)

(II)

(III)

Similarly, $[Pt(Py)(NH_3) BrCl]$ may exist in three isomeric form in which

$M=Pt, A=Py, B=NH_3, C=Br, D=Cl$.



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