Coordination Compounds - Result Question 79

####86. Which of the following organometallic compound is $\sigma$ and $\pi$ bonded?

[2001]

(a) $[Fe(\eta^{5}-C_5 H_5)_2]$

(b) $Fe(CH_3)_3$

(c) $K[PtCl_3(\eta^{2}-C_2 H_4)]$

(d) $[Co(CO)_5 NH_3]^{2+}$

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Solution:

  1. (d) In metal carbonyl complexes, $\sigma$ and $\pi$ both bonds are present because of synergic bonding. Thus, $[Co(CO)_5(NH_3)]^{2+}$ has $\sigma$ and $\pi$ bonding.


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