SATHEE: Coordination Compounds - Result Question 54

Coordination Compounds - Result Question 54

####61. Crystal field stabilization energy for high spin $d^{4}$ octahedral complex is:

[2010]

(a) $- 1.8 Δ_{0}$

(b) $- 1.6 Δ_{0} + P$

(c) $- 1.2 Δ_{0}$

(d) $- 0.6 Δ_{0}$

Show Answer

Solution:

(d) $d^{4}$ in high spin octahedral complex

$\begin{aligned} \begin{array}{c} e_{g} & ↑ & - \\ t_{2 g} & ↑ & ↑ & ↑ \end{array} \\ C F S E = [0.6 \times 1] + [- 0.4 \times 3] = - 0.6 Δ_{0} \end{aligned}$

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