Coordination Compounds - Result Question 53

####60. Which of the following complex ion is not expected to absorb visible light ?

[2010]

(a) $[Ni(CN)_4]^{2-}$

(b) $[Cr(NH_3)_6]^{3+}$

(c) $[Fe(H_2 O)_6]^{2+}$

(d) $[Ni(H_2 O)_6]^{2+}$

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Solution:

(a) $[Ni(CN)_4]^{2-}:$ Number ofunpaired electrons $=0$

$[Cr(NH_3)_6]^{3+}:$ Number of unpaired electrons $=3$

$[Fe(H_2 O)_6]^{2+}:$ Number of unpaired electrons $=4$

$[Ni(H_2 O)_6]^{2+}:$ Number of unpaired electrons $=2$



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