Coordination Compounds - Result Question 49

####55. Red precipitate is obtained when ethanol solution of dimethylglyoxime is added to ammoniacal Ni(II). Which of the following statements is not true?

[2012 M]

(a) Red complex has a square planar geometry.

(b) Complex has symmetrical H-bonding

(c) Red complex has a tetrahedral geometry.

(d) Dimethylglyoxime functions as bidentate ligand.

Show Answer

Solution:

  1. (c) Nickel ions are frequently detected by the formation of red precipitate of the complex of nickel dimethylglyoxime, when heated with dimethylglyoxime.

CH3C=NOHCH3C=NOH+Ni2+

Dimethylglyoxime

Nickel dimethylglyoxime

Ni2+=1L|1/1/1|113d4s4p

dmg is a strong field ligand, so electrons will rearrange as:

Thus, the complex is square plan ar geometry.



NCERT Chapter Video Solution

Dual Pane