Coordination Compounds - Result Question 24

####26. Which one of the following complexes will have four different isomers?

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(a) $[Co(en)_2 Cl_2] Cl$

(b) $[Co(.$ en $.)(NH_3)_2 Cl_2] Cl$

(c) $[Co(PPh_3)_2 Cl_2] Cl$

(d) $[Co(en)_3] Cl_3$

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Solution:

  1. (b) Complex $[Co(en)(NH_3)_2 Cl_2] Cl$ will have four different isomers.

(i) Geometrical isomersNC(N)(Cl)Cl

(ii) Optical isomersNC(Cl)(Cl)Cl

cis-isomer (no element of symmetry)

Hence, the compound has 4 different isomers



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