Coordination Compounds - Result Question 18

####20. Which one of the following octahedral complexes will not show geometric isomerism? ( $A$ and $B$ are monodentate ligands)

[2003]

(a) $[MA_5 B]$

(b) $[MA_2 B_4]$

(c) $[MA_3 B_3]$

(d) $[MA_4 B_2]$

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Solution:

(a) $MA_3 B_3-2$ geometrical isomers

$MA_2 B_4-2$ geometrical isomers

$MA_4 B_2-2$ geometrical isomers

The complexes of general formula $Ma_6$ and $Ma_5 b$ octahedral geometry do not show geometrical isomerism.



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