SATHEE: Coordination Compounds - Result Question 18

Coordination Compounds - Result Question 18

####20. Which one of the following octahedral complexes will not show geometric isomerism? ( $A$ and $B$ are monodentate ligands)

[2003]

(a) $[M A_{5} B]$

(b) $[M A_{2} B_{4}]$

(d) $[M A_{4} B_{2}]$

Show Answer

Solution:

(a) $M A_{3} B_{3} - 2$ geometrical isomers

$M A_{2} B_{4} - 2$ geometrical isomers

$M A_{4} B_{2} - 2$ geometrical isomers

The complexes of general formula $M a_{6}$ and $M a_{5} b$ octahedral geometry do not show geometrical isomerism.

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Coordination Compounds - Result Question 18

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