Coordination Compounds - Result Question 13

####15. Which of the following will give a pair of enantiomorphs?

[2007]

(a) $[Cr(NH_3)_6][Co(CN)_6]$

(b) $[Co(en)_2 Cl_2] Cl$

(c) $[Pt(NH_3)_4][PtCl_6]$

(d) $[Co(NH_3)_4 Cl_2] NO_2$. $(en=NH_2 CH_2 CH_2 NH_2)$

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Solution:

  1. (b) Non superimposable mirror images are called optical isomers and may be described as ‘chiral’. They are also called enantiomers and rotate plane polarised light in opposite directions.Cl[W]1(Cl)(Cl)NCCN1ClC1(Cl)N2CCN(C2)C1(Cl)Cl


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