SATHEE: Coordination Compounds - Result Question 1

Coordination Compounds - Result Question 1

####1. The type of isomerism shown by the complex $[C o C l_{2} (e n)_{2}]$ is

[2018]

(a) Geometrical isomerism

(b) Coordination isomerism

(c) Linkage isomerism

(d) Ionization isomerism

Show Answer

Solution:

(b) $[C o (N H_{3})_{6}] C l_{3} \overset{A g N O_{3}}{\to}$

$[C o (N H_{3})_{5} C l] C l_{2} \overset{A g N O_{3}}{\to}$

$2 m o l$ of $A g C l$

$[C o (N H_{3})_{4} C l_{2}] C l \overset{A g N O_{3}}{\to} 1 m o l$ of $A g C l$

Complexes are respectively $[C o (N H_{3})_{6}] C l_{3}$ , $[C o (N H_{3})_{5} C l] C l_{2}$ and $[C o (N H_{3})_{4} C l_{2}] C l$

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