Chemical Kinetics - Result Question 30

####30. Half life period of a first-order reaction is 1386 seconds. The specific rate constant of the reaction is:

[2009]

(a) $0.5 \times 10^{-2} s^{-1}$

(b) $0.5 \times 10^{-3} s^{-1}$

(c) $5.0 \times 10^{-2} s^{-1}$

(d) $5.0 \times 10^{-3} s^{-1}$

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Solution:

  1. (b) For a first order reaction

$t _{1 / 2}=\frac{0.693}{k} ; k=\frac{0.693}{1386}=0.5 \times 10^{-3} s^{-1}$



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