Chemical Kinetics - Result Question 15

####15. For the reaction $2 N_2 O_5 \to 4 NO_2+O_2$, rate and rate constant are $1.02 \times 10^{-4} mol lit^{-1} s^{-1}$ and $3.4 \times 10^{-5} s^{-1}$ respectively then concentration of $N_2 O_5$ at that time will be

(a) $1.732 M$

(b) $3 M$

(c) $3.4 \times 10^{5} M$

(d) $1.02 \times 10^{-4} M$

[2001]

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Solution:

  1. (b) $2 N_2 O_5 \to 4 NO_2+O_2$

From the unit of rate constant, it is clear that the reaction follow first order kinetics. Hence, by rate law equation, $\quad r=k[N_2 O_5]$ where $r=1.02 \times 10^{-4}, k=3.4 \times 10^{-5}$

$1.02 \times 10^{-4}=3.4 \times 10^{-5}[N_2 O_5]$

$[N_2 O_5]=3 M$



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