Chemical Bonding and Molecular Structure - Result Question 97

####99. Decreasing order of stability of O2,O2,O2+and O22 is :

[2015 RS]

(a) O2+>O2>O2>O22

(b) O22>O2>O2>O2+

(c) O2>O2+>O22>O2

(d) O2>O22>O2+>O2

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Solution:

  1. (a) According to molecular orbital theory as bond order decreases stability of the molecule decreases

Bond order =12(NbNa)

Bond order for O2+=12(105)=2.5

Bond order for O2=12(106)=2

Bond order for O2=12(107)=1.5

Bond order for O22=12(108)=1.0

hence the correct order is

O2+>O2>O2>O22



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