Chemical Bonding and Molecular Structure - Result Question 93

####95. Which of the following pairs of species have the same bond order?

[2017]

(a) O2,NO+

(b) CN,CO

(c) N2,O2

(d) CO,NO

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Solution:

  1. (b) CNand CO have same no. of electrons and have same bond order equal to 3 .

Short cut trick to calculate the bond order:

N2 has 14 electrons and its bond order is 3 . We have to remember this concept that every electron added or subtracted to 14 , reduces the bond order by 0.5 . For example

CN no. of electrons =6+7+1=14

bond order =3

CO no. of electrons =6+8=14

bond order =3

NO no. of electrons =7+8=15

bond order =30.5=2.5

NO+ no. of electrons =7+81=14

bond order =3

O2 no. of electrons =8+8+1=17

bond order =31.5

Please note that this method will work for any species that have electrons between 10 and 18 .



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