Chemical Bonding and Molecular Structure - Result Question 64

####65. In BrF3 molecule, the lone pairs occupy equatorial positions to minimize

(a) lone pair - bond pair repulsion only

(b) bond pair - bond pair repulsion only

(c) lone pair - lone pair repulsion and lone pair - bond pair repulsion

(d) lone pair - lone pair repulsion only

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Solution:

  1. (c) The possible structures are:

90lplp

repulsion 0

90lpbp

repulsion 4

90bpbp

repulsion 2

The first structure is minimizing the lplp repulsion if we compare it with III. The same is minimizing the lpbp repulsions if we compare it with II. Also it can be noted that, I structure is not minimizing the bpbp repulsions.

1

3

2

02



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