Chemical Bonding and Molecular Structure - Result Question 59

####60. In which of the following pairs, the two species are isostructural?

[2007]

(a) $SO_3{ }^{2-}$ and $NO_3{ }^{-}$

(b) $BF_3$ an $NF_3$

(c) $BrO_3{ }^{-}$and $XeO_3$

(d) $SF_4$ and $XeF_4$

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Solution:

  1. (c) Hybridization of $Br$ in $BrO_3^{-}$

$H=\frac{1}{2}(7+0-0+1)=4$

hybridization $=s p^{3}$

Hybridization of $Xe$ in $XeO_3$.

$H=\frac{1}{2}(8+0-0+0)=4$

Hybridization $=s p^{3}$

In both cases, the structure is trigonal pyramidal.



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