Chemical Bonding and Molecular Structure - Result Question 50

####51. Which one of the following pairs is isostructural (i.e., having the same shape and hybridization)?

(a) $[BCl_3.$ and $.BrCl_3^{-}]$

[2012]

(b) $[NH_3.$ and $.NO_3^{-}]$

(c) $[NF_3.$ and $.BF_3]$

(d) $[BF_4^{-}.$and $.NH_4^{+}]$

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Solution:

  1. (d) $BF_4^{-}$hybridisation $s p^{3}$, tetrahedral structure.

$NH_4^{+}$hybridisation $s p^{3}$, tetrahedral structure.



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