Chemical Bonding and Molecular Structure - Result Question 16

####16. Which of the following is not a correct statement?

[2006]

(a) The cannonical structures have no real existence

(b) Every $A B_5$ molecule does in fact have square pyramidal structure

(c) Multiple bonds are always shorter than corresponding single bonds

(d) The electron-deficient molecules can act as Lewis acids

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Solution:

  1. (b) Statement (a), (c), (d) are correct. Statement (b) is incorrect statement.

$A B_5$ may have two structures as follows :

Square Pyramidal

Trigonal Bipyramidal Individual cannonical structures do not exist. The molecule as such has a single structure, which is the resonance hybrid of the cannonical forms.



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