Chemical Bonding and Molecular Structure - Result Question 16

####16. Which of the following is not a correct statement?

[2006]

(a) The cannonical structures have no real existence

(b) Every AB5 molecule does in fact have square pyramidal structure

(c) Multiple bonds are always shorter than corresponding single bonds

(d) The electron-deficient molecules can act as Lewis acids

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Solution:

  1. (b) Statement (a), (c), (d) are correct. Statement (b) is incorrect statement.

AB5 may have two structures as follows :

Square Pyramidal

Trigonal Bipyramidal Individual cannonical structures do not exist. The molecule as such has a single structure, which is the resonance hybrid of the cannonical forms.



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