Chemical Bonding and Molecular Structure - Result Question 100

####102. In which of the following ionisation processes the bond energy increases and the magnetic behaviour changes from paramagnetic to diamagnetic?

[NEET Kar. 2013]

(a) $N_2 \to N_2^{+}$

(c) $C_2 \to C_2^{+}$

(b) $O_2 \to O_2^{+}$

(d) $NO \to NO^{+}$

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Solution:

$ \begin{aligned} & \text{ (d) (a) } \\ & N_2 \longrightarrow N_2^{+} \\ & \text{B.O. } 3 \quad 2.5 \end{aligned} $

Bond energy decreases Magnetic behaviour changes from diamagnetic to paramagnetic

(b)

Bond energy increases

Magnetic behaviour does not change. (c) $\quad C_2 \longrightarrow C_2^{+}$

B.O. $2 \quad 2.5$

Bond energy decreases

Magnetic behaviour changes from diamagnetic to paramagnetic

(d)

$ NO \longrightarrow NO^{+} $

B.O. 22.5

bond energy increases

Magnetic behaviour changes from paramagnetic to diamagnetic



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