Chemical and Ionic Equilibrium 1 Question 20

21. For the reversible reaction,

$$ \mathrm{N}{2}(g)+3 \mathrm{H}{2}(g) \rightleftharpoons 2 \mathrm{NH}_{3}(g) $$

at 500C, the value of Kp is 1.44×105 when partial pressure is measured in atmosphere. The corresponding value of Kc with concentration in mol/L is

(2000,5,1M)

(a) 1.44×105(0.082×500)2

(b) 1.44×105(8.314×773)2

(c) 1.44×105(0.082×773)2

(d) 1.44×105(0.082×773)2

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Solution:

  1. $\mathrm{N}{2}(g)+3 \mathrm{H}{2}(g) \rightleftharpoons 2 \mathrm{NH}_{3}(g)$

Δn=2

Kp=Kc(RT)Δn Kc=Kp(RT)Δn=1.44×105(0.082×773)2