Amines - Result Question 44

####46. What is the product obtained in the following reaction :

[2011]

(a)ONc1ccccc1

(b)c1ccc(/N=N/c2ccccc2)cc1

(c)[O-]N([I+]=Nc1ccccc1)c1ccccc1

(d)Nc1ccccc1

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Solution:

  1. (a) When nitro compound is reduced with a neutral reducing agent $(Zn.$ dust $.+NH_4 Cl)$ the corresponding hydroxyl amine is formed

$C_6 H_5 NO_2+4[H] \xrightarrow{Zn \text{ dust }+NH_4 Cl}$

$C_6 H_5 NHOH$



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