Amines - Result Question 32

####34. Intermediates formed during reaction of

RCNH2 O  with Br2 and KOH are 

(a) RNHBr and RCONHBr

(b) RNHCOBr and RNCO

(c) RCONHBr and RNCO

(d) RCONBr2

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Solution:

  1. (c) The mechanism of Hoffmann bromamide reaction is

(i) RCONH2+Br2RCONHBr+HBr

(ii) RCONHBr+HBrOH

RCON¨Br+H2O (iii)

(iv)

(v) RN¨=C=O+2KOHRNH2+K2CO3



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