Amines - Result Question 3

####3. The correct order of the basic strength of methyl substituted amines in aqueous solution is :

(a) $(CH_3)_2 NH>CH_3 NH_2>(CH_3)_3 N$

[2019]

(b) $(CH_3)_3 N>CH_3 NH_2>(CH_3)_2 NH$

(c) $(CH_3)_3 N>(CH_3)_2 NH>CH_3 NH_2$

(d) $CH_3 NH_2>(CH_3)_2 NH>(CH_3)_3 N$

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Solution:

  1. (a) Account for the inductive effect, solvation effect (H-bonding.) and steric hinderance for basic character in aqueous solutions


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