Amines - Result Question 25

####27. The following reactionNc1ccccc1

is known by the name :

[2015 RS]

(a) Friedel-Craft’s reaction

(b) Perkin’s reaction

(c) Acetylation reaction

(d) Schotten-Baumen reaction

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Solution:

  1. (d)

$ \begin{matrix} NH_3 & CH_3 NH_2 \\ K_b=1.8 \times 10^{-5} & 44 \times 10^{-5} \end{matrix} $

$ \xrightarrow[CH_3 Cl]{AlCl_3} $

(a)Cc1ccccc1C(C)(C)C(C)(C)C(C)(C)C

(b)[R]CC(=O)OC(=O)C[R] Perkin Reaction[R]CC(=O)O

(c)CC(=O)C+(C)C(=O)ClCC(=O)Oc1ccccc1

(d)Nc1ccccc1 Schotten-Baumen ReactionO=C(Nc1ccc(O)cc1)c1ccccc1



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