Alcohols Phenols and Ethers - Result Question 56

####57. Among the following ethers, which one will produce methyl alcohol on treatment with hot concentrated $HI$ ?

[NEET 2013]

(a)CCC(C)OC

(b)COC(C)(C)C

(c)COCC(C)C

(d) $CH_3-CH_2-CH_2-CH_2-O-CH_3$

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Solution:

  1. (b) The reaction will proceed via $S_N 1$ mechanism because alkyl group attached is $3^{\circ}$.COC(C)(C)CCC(C)(C)C(C)(C)C(C)(C)C

(Highly stable)

When tertiary alkyl group is attached then it forms alkyl iodide because of the stability of tertiary carbocation.



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