Alcohols Phenols and Ethers - Result Question 43

####44. Correct increasing order of acidity is as follows:

[1994]

(a) H2O,C2H2,H2CO3, Phenol

(b) C2H2,H2O,H2CO3, Phenol

(c) Phenol, C2H2,H2CO3,H2O

(d) C2H2,H2O, Phenol, H2CO3

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Solution:

  1. (d) Such questions can be solved by considering the relative basic character of their conjugated bases which for H2O,C2H2,H2CO3 and C6H5OH are

OH,HC=C,HCO3,C6H5O

More the possibility for the dispersal of the negative charge, weaker will be the base. Thus the relative basic character of the four bases is

HCO3<C6H5O<OH<HC=C

Equivalent Non-equivalent Oxygen can accommodate

resonating structures () charge easily

Due to resonance

Thus, the acidic character of the four corresponding acids wil be

HC=CH<H2O<C6H5OH<H2CO3



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