Alcohols Phenols and Ethers - Result Question 37

####38. Which one of the following compounds is most acidic?

[2005] (a) $Cl-CH_2-CH_2-OH$

(c)O=N+c1ccccc1O

(d)Oc1ccccc1Cc1ccccc1O

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Solution:

  1. (c) Phenols are more acidic than alcohols as they are resonance stabilised whereas alcohols are not.

Further $-NO_2$ is an electron withdrawing group which increases acidic character and facilitates release of proton, whereas $-CH_3$ is an electron donating group which decreases acidic character, thus removal of $H^{+}$becomes difficult.



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