Thermal Properties of Matter

Multiple Choice Questions (MCQs)

1. A bimetallic strip is made of aluminium and steel $(\alpha_{A l}>\alpha_{\text {steel }})$. On heating, the strip will

(a) remain straight

(b) get twisted

(c) will bend with aluminium on concave side

(d) will bend with steel on concave side

Show Answer

Thinking Process

The metallic strip with higher coefficient of linear expansion $(\alpha_{\text {Al }})$ will expand more.

Answer (d) As $\alpha_{\text {Al }}>\alpha$ steal, aluminium will expand more. So, it should have larger radius of curvature. Hence, aluminium will be on convex side.

  • (a) remain straight: This option is incorrect because the two metals have different coefficients of thermal expansion. When heated, they will expand by different amounts, causing the strip to bend rather than remain straight.

  • (b) get twisted: This option is incorrect because twisting would imply a non-uniform expansion or some form of torsional stress, which is not the case here. The strip will bend uniformly due to the difference in thermal expansion coefficients.

  • (c) will bend with aluminium on concave side: This option is incorrect because aluminium has a higher coefficient of thermal expansion than steel. Therefore, aluminium will expand more and will be on the convex side, not the concave side.

2. A uniform metallic rod rotates about its perpendicular bisector with constant angular speed. If it is heated uniformly to raise its temperature slightly

(a) its speed of rotation increases

(b) its speed of rotation decreases

(c) its speed of rotation remains same

(d) its speed increases because its moment of inertia increases

Show Answer

Answer (b) As the rod is heated, it expands. No external torque is acting on the system so angular momentum should be conserved.

$$ \begin{aligned} & \quad L=\text { Angular momentum }=I \omega=\text { constant } \\ & \Rightarrow \quad I_1 \omega_1=I_2 \omega_2 \end{aligned} $$

Due to expansion of the rod $I_2>I_1$

$$ \begin{matrix} \Rightarrow & \frac{\omega_2}{\omega_1}=\frac{I_1}{I_2}<1 \\ \Rightarrow & \omega_2<\omega_1 \end{matrix} $$

So, angular velocity (speed of rotation) decreases.

  • Option (a) its speed of rotation increases: This is incorrect because when the rod is heated and expands, its moment of inertia increases. Since no external torque is acting on the system, angular momentum must be conserved. An increase in the moment of inertia results in a decrease in angular velocity, not an increase.

  • Option (c) its speed of rotation remains same: This is incorrect because the expansion of the rod due to heating changes its moment of inertia. Since angular momentum is conserved and the moment of inertia increases, the angular velocity must decrease to maintain the conservation of angular momentum.

  • Option (d) its speed increases because its moment of inertia increases: This is incorrect because an increase in the moment of inertia actually leads to a decrease in angular velocity when angular momentum is conserved. The relationship is inversely proportional, not directly proportional.

3. The graph between two temperature scales $A$ and $B$ is shown in figure between upper fixed point and lower fixed point there are 150 equal division on scale $A$ and 100 on scale $B$. The relationship for conversion between the two scales is given by

(a) $\frac{t_{A}-180}{100}=\frac{t_{B}}{150}$

(b) $\frac{t_{A}-30}{150}=\frac{t_{B}}{100}$

(c) $\frac{t_{B}-180}{150}=\frac{t_{A}}{100}$

(d) $\frac{t_{B}-40}{100}=\frac{t_{A}}{180}$

Show Answer

Answer (b) It is clear from the graph that lowest point for scale $A$ is $30^{\circ}$ and lowest point for scale $B$ is $0^{\circ}$. Highest point for the scale $A$ is $180^{\circ}$ and for scale $B$ is $100^{\circ}$. Hence, correct relation is

$\Rightarrow \frac{t_{A}-30}{180-30}=\frac{t_{B}-0}{100-0}$

$\Rightarrow \quad \frac{t_{A}-30}{150}=\frac{t_{B}}{100}$

where, LFP $\rightarrow$ Lower fixed point

UFP $\rightarrow$ Upper fixed point

  • Option (a): The equation $\frac{t_{A}-180}{100}=\frac{t_{B}}{150}$ is incorrect because it incorrectly assumes that the lower fixed point for scale $A$ is $180^{\circ}$ and the lower fixed point for scale $B$ is $0^{\circ}$. The correct lower fixed point for scale $A$ is $30^{\circ}$, not $180^{\circ}$.

  • Option (c): The equation $\frac{t_{B}-180}{150}=\frac{t_{A}}{100}$ is incorrect because it incorrectly assumes that the lower fixed point for scale $B$ is $180^{\circ}$. The correct lower fixed point for scale $B$ is $0^{\circ}$, not $180^{\circ}$.

  • Option (d): The equation $\frac{t_{B}-40}{100}=\frac{t_{A}}{180}$ is incorrect because it incorrectly assumes that the lower fixed point for scale $B$ is $40^{\circ}$. The correct lower fixed point for scale $B$ is $0^{\circ}$, not $40^{\circ}$. Additionally, it incorrectly assumes that the upper fixed point for scale $A$ is $180^{\circ}$ without considering the correct lower fixed point for scale $A$.

4. An aluminium sphere is dipped into water. Which of the following is true?

(a) Buoyancy will be less in water at $0^{\circ} C$ than that in water at $4^{\circ} C$

(b) Buoyancy will be more in water at $0^{\circ} C$ than that in water at $4^{\circ} C$

(c) Buoyancy in water at $0^{\circ} C$ will be same as that in water at $4{ }^{\circ} C$

(d) Buoyancy may be more or less in water at $4^{\circ} C$ depending on the radius of the sphere

Show Answer

Thinking Process

Density of water is maximum at $4{ }^{\circ} C$, this is because of anomalous expansion of water.

Answer (a) Let volume of the sphere is $V$ and $\rho$ is its density, then we can write buoyant force

$\begin{aligned} & F=V \rho G \quad(g=\text { acceleration due to gravity }) \\ & \Rightarrow \quad F \propto \rho \quad(\because V \text { and } g \text { are almost constant }) \\ & \Rightarrow \quad \frac{F_{4 C}}{F_{0 C}}=\frac{\rho_{4 C}}{\rho_{0 C}}>1 \quad\left(\because \rho_{4 C}>\rho_{0 C}\right) \\ & \Rightarrow \quad F_{4 C}>F_{0 C} \\ \end{aligned}$

Hence, buoyancy will be less in water at $0^{\circ} C$ than that in water at $4^{\circ} C$.

  • (b) Buoyancy will be more in water at $0^{\circ} C$ than that in water at $4^{\circ} C$: This is incorrect because the density of water is higher at $4^{\circ} C$ than at $0^{\circ} C$. Since buoyant force is directly proportional to the density of the fluid, the buoyant force will be greater in water at $4^{\circ} C$.

  • (c) Buoyancy in water at $0^{\circ} C$ will be same as that in water at $4^{\circ} C$: This is incorrect because the density of water changes with temperature. The density of water is maximum at $4^{\circ} C$, so the buoyant force will not be the same at $0^{\circ} C$ and $4^{\circ} C$.

  • (d) Buoyancy may be more or less in water at $4^{\circ} C$ depending on the radius of the sphere: This is incorrect because the buoyant force depends on the volume of the displaced fluid and the density of the fluid, not on the radius of the sphere. The density of water at $4^{\circ} C$ is higher than at $0^{\circ} C$, so the buoyant force will always be greater at $4^{\circ} C$ regardless of the radius of the sphere.

5. As the temperature is increased, the period of a pendulum

(a) increases as its effective length increases even though its centre of mass still remains at the centre of the bob

(b) decreases as its effective length increases even though its centre of mass still remains at the centre of the bob

(c) increases as its effective length increases due to shifting to centre of mass below the centre of the bob

(d) decreases as its effective length remains same but the centre of mass shifts above the centre of the bob

Show Answer

Answer (a) As the temperature is increased length of the pendulum increases. We know that time period of pendulum $T=2 \pi \sqrt{\frac{L}{g}}$

$$ \Rightarrow \quad T \propto \sqrt{L} \text {, as } L \text {, increases. } $$

So, time period $(T)$ also increases.

  • (b) The period of a pendulum does not decrease as its effective length increases. According to the formula ( T = 2\pi \sqrt{\frac{L}{g}} ), the period ( T ) is directly proportional to the square root of the length ( L ). Therefore, if the length increases, the period must also increase, not decrease.

  • (c) The period of a pendulum increases due to the increase in the effective length, not because of the shifting of the center of mass below the center of the bob. The center of mass of the bob remains at the center, and the increase in period is solely due to the increase in length.

  • (d) The period of a pendulum does not decrease if the effective length remains the same. The formula ( T = 2\pi \sqrt{\frac{L}{g}} ) shows that the period is dependent on the length ( L ). If the length does not change, the period will not decrease. Additionally, the center of mass shifting above the center of the bob is not a factor in the period of a pendulum.

6. Heat is associated with

(a) kinetic energy of random motion of molecules

(b) kinetic energy of orderly motion of molecules

(c) total kinetic energy of random and orderly motion of molecules

(d) kinetic energy of random motion in some cases and kinetic energy of orderly motion in other

Show Answer

Answer (a) We know that as temperature increases vibration of molecules about their mean position increases hence, kinetic energy associated with random motion of molecules increases.

  • (b) Kinetic energy of orderly motion of molecules: Heat is not associated with the orderly motion of molecules. Orderly motion refers to a uniform or structured movement, which is characteristic of macroscopic objects rather than the microscopic random motion of molecules that constitutes heat.

  • (c) Total kinetic energy of random and orderly motion of molecules: Heat specifically refers to the kinetic energy due to random motion of molecules. The inclusion of orderly motion in this option makes it incorrect because heat does not account for the kinetic energy from orderly motion.

  • (d) Kinetic energy of random motion in some cases and kinetic energy of orderly motion in other: Heat is consistently associated with the random motion of molecules. It does not switch between random and orderly motion depending on the case. This option is incorrect because it suggests a variability that does not exist in the definition of heat.

7. The radius of a metal sphere at room temperature $T$ is $R$ and the coefficient of linear expansion of the metal is $\alpha$. The sphere heated a little by a temperature $\Delta T$ so that its new temperature is $T+\Delta T$. The increase in the volume of the sphere is approximately.

(a) $2 \pi R \alpha \Delta T$

(b) $\pi R^{2} \alpha \Delta T$

(c) $4 \pi R^{3} \alpha \Delta T / 3$

(d) $4 \pi R^{3} \alpha \Delta T$

Show Answer

Answer (d) Let the radius of the sphere is $R$. As the temperature increases radius of the sphere increases as shown.

$ \text { Original volume } V_0=\frac{4}{3} \pi R^{3} $

Coefficient of linear expansion $=\alpha$

$\therefore \quad$ Coefficient of volume expansion $=3 \alpha$

$\therefore \quad \frac{1}{V} \frac{d V}{d T}=3 \alpha \Rightarrow d V=3 V \alpha d t=4 \pi R^{3} \alpha \Delta T$

$=$ Increase in the volume

  • Option (a): $2 \pi R \alpha \Delta T$

    • This option is incorrect because it suggests a linear relationship between the increase in volume and the temperature change. However, the volume expansion of a sphere is a cubic relationship, not linear. The correct factor should involve $R^3$ rather than $R$.
  • Option (b): $\pi R^{2} \alpha \Delta T$

    • This option is incorrect because it suggests a quadratic relationship between the increase in volume and the temperature change. The volume expansion of a sphere is a cubic relationship, not quadratic. The correct factor should involve $R^3$ rather than $R^2$.
  • Option (c): $4 \pi R^{3} \alpha \Delta T / 3$

    • This option is incorrect because it underestimates the increase in volume by a factor of 3. The coefficient of volume expansion is $3\alpha$, and when applied to the original volume $\frac{4}{3} \pi R^3$, the correct increase in volume should be $4 \pi R^3 \alpha \Delta T$, not $\frac{4 \pi R^3 \alpha \Delta T}{3}$.

8. A sphere, a cube and a thin circular plate, all of same material and same mass are initially heated to same high temperature.

(a) Plate will cool fastest and cube the slowest

(b) Sphere will cool fastest and cube the slowest

(c) Plate will cool fastest and sphere the slowest

(d) Cube will cool fastest and plate the slowest

Show Answer

Thinking Process

In this problem the cooling will be in the form of radiations that is according to Stefan’s law. Since, emissive power directly proportional to surface. Here, for given volume, sphere have least surface area and circular plate of greatest surface area.

Answer (c) Consider the diagram where all the three objects are heated to same temperature $T$. We know that density, $\rho=\frac{\text { mass }}{\text { volume }}$ as $\rho$ is same for all the three objects hence, volume will also be same.

Sphere

Cube

Plate

As thickness of the plate is least hence, surface area of the plate is maximum.

We know that, according to Stefan’s law of heat loss $H \alpha A T^{4}$ where, $A$ is surface area of for object and $T$ is temperature.

Hence,

$$ \begin{aligned} & H_{\text {sphere }}: H_{\text {cube }}: H_{\text {plate }} \\ = & A_{\text {sphere }}: A_{\text {cube }}: A_{\text {plate }} \end{aligned} $$

As $A_{\text {plate }}$ is maximum.

Hence, the plate will cool fastest.

As, the sphere is having minimum surface area hence, the sphere cools slowest.

  • Option (a): Plate will cool fastest and cube the slowest

    • Incorrect because the sphere has a smaller surface area compared to the cube. Since the rate of cooling is proportional to the surface area, the cube will not cool the slowest; the sphere will.
  • Option (b): Sphere will cool fastest and cube the slowest

    • Incorrect because the sphere has the smallest surface area among the three objects. According to Stefan’s law, the object with the smallest surface area will cool the slowest, not the fastest.
  • Option (d): Cube will cool fastest and plate the slowest

    • Incorrect because the plate has the largest surface area, which means it will lose heat the fastest according to Stefan’s law. The cube, having a larger surface area than the sphere but smaller than the plate, will not cool the fastest.

Multiple Choice Questions (More Than One Options)

9. Mark the correct options

(a) A system $X$ is in thermal equilibrium with $Y$ but not with $Z$. The systems $Y$ and $Z$ may be in thermal equilibrium with each other.

(b) A system $X$ is in thermal equilibrium with $Y$ but not with $Z$. The systems $Y$ and $Z$ are not in thermal equilibrium with each other.

(c) A system $X$ is neither in thermal equilibrium with $Y$ nor with $Z$. The systems $Y$ and $Z$ must be in thermal equilibrium with each other.

(d) A system $X$ is neither in thermal equilibrium with $Y$ nor with $Z$. The systems $Y$ and $Z$ may be in thermal equilibrium with each other.

Show Answer

Answer $(b, d)$

According to question

$$T_x=T _y \quad(\because \text{x and y are in thermal equilibrium })$$ $$T _x \neq T_z \quad(\because \text{ x is not in thermal equilibrium with z})$$ $$ \text{Clearly}, T _y \neq T _z$$

Hence, $\quad y$ and $z$ are not in thermal equilibrium. (d) Given, $T_{x} \neq T_{y}$ and $T_{x} \neq T_{z}$

We cannot say about equilibrium of $Y$ and $Z$, they may or may not be in equilibrium.

  • (a) A system (X) is in thermal equilibrium with (Y) but not with (Z). The systems (Y) and (Z) may be in thermal equilibrium with each other.

    • This option is incorrect because if (X) is in thermal equilibrium with (Y) ((T_x = T_y)) and (X) is not in thermal equilibrium with (Z) ((T_x \neq T_z)), then (T_y \neq T_z). Therefore, (Y) and (Z) cannot be in thermal equilibrium with each other.
  • (c) A system (X) is neither in thermal equilibrium with (Y) nor with (Z). The systems (Y) and (Z) must be in thermal equilibrium with each other.

    • This option is incorrect because if (X) is not in thermal equilibrium with (Y) ((T_x \neq T_y)) and (X) is not in thermal equilibrium with (Z) ((T_x \neq T_z)), there is no information to conclude that (Y) and (Z) must be in thermal equilibrium with each other. They may or may not be in thermal equilibrium.

10. Gulab namuns (assumed to be spherical) are to be heated in an oven. They are available in two sizes, one twice bigger (in radius) than the other. Pizzas (assumed to be discs) are also to be heated in oven. They are also in two sizes, one twice bigger (in radius) than the other. All four are put together to be heated to oven temperature. Choose the correct option from the following.

(a) Both size gulab jamuns will get heated in the same time

(b) Smaller gulab jamuns are heated before bigger ones

(c) Smaller pizzas are heated before bigger ones

(d) Bigger pizzas are heated before smaller

Show Answer

Answer $(b, c)$

Smaller gulab jamuns are having least surface area hence, they will be heated first.

As in case of smaller gulab jamun heat radiates will be less

Similarly, smaller pizzas are heated before bigger ones because they are of small surface areas.

  • Option (a): Both size gulab jamuns will get heated in the same time

    • This option is incorrect because the rate of heating depends on the surface area to volume ratio. Smaller gulab jamuns have a higher surface area to volume ratio compared to bigger ones, which means they will heat up faster.
  • Option (d): Bigger pizzas are heated before smaller

    • This option is incorrect because, similar to the gulab jamuns, the rate of heating for pizzas also depends on the surface area to volume ratio. Smaller pizzas have a higher surface area to volume ratio compared to bigger ones, which means they will heat up faster.

11. Refer to the plot of temperature versus time (figure) showing the changes in the state if ice on heating (not to scale). Which of the following is correct?

(a) The region $A B$ represent ice and water in thermal equilibrium

(b) At $B$ water starts boiling

(c) At $C$ all the water gets converted into steam

(d) $C$ to $D$ represents water and steam in equilibrium at boiling point

Show Answer

Thinking Process

During phase change process, temperature of the system remains constant.

Answer $(a, d)$

During the process $A B$ temperature of the system is $0^{\circ} C$ Hence, it represents phase change that is transformation of ice into water while temperature remains $0^{\circ} C$.

$B C$ represents rise in temperature of water from $0^{\circ} C$ to $100^{\circ} C$ (at $C$ ).

Now, water starts converting into steam which is represent by $C D$.

  • Option (b): At point B, water does not start boiling. Instead, point B marks the end of the phase change from ice to water, and the temperature of the water begins to rise from 0°C to 100°C.

  • Option (c): At point C, not all the water gets converted into steam. Point C represents the temperature at which water starts to boil (100°C), but the phase change from water to steam occurs over the region from C to D.

12. A glass full of hot milk is poured on the table. It begins to cool gradually. Which of the following is correct?

(a) The rate of cooling is constant till milk attains the temperature of the surrounding

(b) The temperature of milk falls off exponentially with time

(c) While cooling, there is a flow of heat from milk to the surrounding as well as from surrounding to the milk but the net flow of heat is from milk to the surrounding and that is why it cools

(d) All three phenomenon, conduction, convection and radiation are responsible for the loss of heat from milk to the surroundings

Show Answer

Answer $(b, c, d)$

When hot milk spread on the table heat is transferred to the surroundings by conduction, convection and radiation.

According to Newton’s law of cooling temperature of the milk falls off exponentially. Heat also will be transferred from surroundings to the milk but will be lesser than that of transferred from milk to the surroundings.

  • Option (a) is incorrect because the rate of cooling is not constant. According to Newton’s law of cooling, the rate of cooling depends on the temperature difference between the milk and the surroundings, which decreases over time. Therefore, the rate of cooling decreases as the milk approaches the temperature of the surroundings.

Very Short Answer Type Questions

13. Is the bulb of a thermometer made of diathermic or adiabatic wall?

Show Answer Answer As diathermic walls alow exchange of heat energy between two systems and adiabatic walls do not, hence, diathermic walls are used to make the bulb of a thermometer.

14. A student records the initial length $l$, change in temperature $\Delta T$ and change in length $\Delta l$ of a rod as follows

S. No. $\boldsymbol{l}(m)$ $\Delta \boldsymbol{T}({ }^{\circ} C)$ $\Delta \boldsymbol{l}(m)$
1. 2 10 $4 \times 10^{-4}$
2. 1 10 $4 \times 10^{-4}$
3. 2 20 $2 \times 10^{-4}$
4. 3 10 $6 \times 10^{-4}$

If the first observation is correct, what can you say about observation 2, 3 and 4.

Show Answer

Answer From the 1st observation $\alpha=\frac{\Delta l}{l \Delta T} \Rightarrow \alpha=\frac{4 \times 10^{-4}}{2 \times 10}=2 \times 10^{-5}{ }^{\circ} C^{-1}$

For 2nd observation

$$ \begin{aligned} \Delta l & =\alpha l \Delta T \\ & =2 \times 10^{-5} \times 1 \times 10=2 \times 10^{-4} m \neq 4 \times 10^{-4} m \text { (Wrong) } \end{aligned} $$

For 3rd observation $\Delta l=\alpha l \Delta T$

$$ =2 \times 10^{-5} \times 2 \times 20=8 \times 10^{-4} m \neq 2 \times 10^{-4} m(\text { Wrong }) $$

For 4th observation

$$ \Delta l=\alpha l \Delta T $$

$$ =2 \times 10^{-5} \times 3 \times 10=6 \times 10^{-4} m=6 \times 10^{-4} m $$

[i.e., observed value (Correct)]

15. Why does a metal bar appear hotter than a wooden bar at the same temperature? Equivalently it also appears cooler than wooden bar if they are both colder than room temperature.

Show Answer

Thinking Process

According to Kirchhoff’s law, good radiator are good absorbers.

Answer Due to difference in conductivity, metals having high conductivity compared to wood. On touch with a finger, heat from the surrounding flows faster to the finger from metals and so one feels the heat.

Similarly, when one touches a cold metal the heat from the finger flows away to the surroundings faster.

16. Calculate the temperature which has numeral value on Celsius and Fahrenheit scale.

Show Answer

Answer Let $Q$ be the value of temperature having same value an Celsius and Fahrenheit scale. Now, we can write

$\frac{{ }^{\circ} F-32}{180} =\frac{{ }^{\circ} C}{100} $

$\Rightarrow \text { Let } \frac{F}{} =C=Q $

$\Rightarrow \frac{Q-32}{180} =\frac{Q}{100}=Q=-40^{\circ} C \text { or }-40^{\circ} F$

17. These days people use steel utensiles with copper bottom. This is supposed to be good for uniform heating of food. Explain this effect using the fact that copper is the better conductor.

Show Answer

Answer As copper is a good conductor of heat as compared to steel. The steel utensils with copper bottom absorbs heat more quickly than steel and give it to the food in utensil. As a result, of it, the food in utensil is heated uniformly and quickly.

Short Answer Type Questions

18. Find out the increase in moment of inertia $I$ of a uniform rod (coefficient of linear expansion $\alpha$ ) about its perpendicular bisector when its temperature is slightly increased by $\Delta T$.

Show Answer

Thinking Process

As temperature increases length of the rod also increases hence, moment of inertia of the rod also increases.

Answer Let the mass and length of a uniform rod be $M$ and $l$ respectively.

Moment of inertia of the rod about its perpendicular bisector. $(I)=\frac{M l^{2}}{12}$

Increase in length of the rod when temperature is increased by $\Delta T$, is given by

$\begin{aligned} \Delta l & =l \cdot \alpha \Delta T \\ \therefore \text { New moment of inertia of the } rod(I) & =\frac{M}{12}(l+\Delta l)^{2}=\frac{M}{12}(l^{2}+\Delta l^{2}+2 I \Delta l)\end{aligned}$

As change in length $\Delta l$ is very small, therefore, neglecting $(\Delta l)^{2}$, we get

$\therefore$ Increase in moment of inertia

$$ \begin{aligned} I^{\prime} & =\frac{M}{12}(l^{2}+2 l \Delta l) \\ & =\frac{M l^{2}}{12}+\frac{M I \Delta l}{6}=l+\frac{M I \Delta l}{6} \end{aligned} $$

$\Delta I=l-I=\frac{M l \Delta l}{6}=2 \times(\frac{M l^{2}}{12}) \frac{\Delta l}{l}$

$\Delta I=2 \cdot I \alpha \Delta T$

[Using Eq. (i)]

19. During summers in India, one of the common practice to keep cool is to make ice balls of crushed ice, dip it in flavoured sugar syrup and sip it. For this a stick is inserted into crushed ice and is squeezed in the palm to make it into the ball. Equivalently in winter in those areas where it snows, people make snow balls and throw around. Explain the formation of ball out of crushed ice or snow in the light of $p-T$ diagram of water.

Show Answer

Answer Refer to the $p-T$ diagram of water and double headed arrow. Increasing pressure at $0^{\circ} C$ and $1 atm$ takes ice into liquid state and decreasing pressure in liquid state at $0^{\circ} C$ and $1 atm$ takes water to ice state.

When crushed ice is squeezed, some of it melts, filling up gap between ice flakes upon releasing pressure. This water freezes, binding all ice flakes and making the ball more stable.

0. 100 g of water is supercooled to $-10^{\circ} C$. At this point, due to some disturbance mechanised or otherwise some of it suddenly freezes to ice. What will be the temperature of the resultant mixture and how much mass would freeze? $[S_{w}=1 cal / g /{ }^{\circ} C.$ and $.L_{\text {Fusion }}^{w}=80 cal / g]$

Show Answer

Answer Given, mass of water $(m)=100$

Change in temperature $\Delta T=0-(-10)=10^{\circ} C$

Specific heat of water $(S_{w})=1 cal / g /{ }^{\circ} C$

Latent heat of fusion of water $L_{\text {fusion }}^{w}=80 cal / g$

Heat required to bring water in super cooling from $-10^{\circ} C$ to $0^{\circ} C$,

$$ \begin{aligned} Q & =m s_{w} \Delta T \\ & =100 \times 1 \times 10=1000 cal \end{aligned} $$

Let $m$ gram of ice be melted.

$$ \begin{matrix} \therefore & Q=m L \\ \text { or } & m=\frac{Q}{L}=\frac{1000}{80}=12.5 g \end{matrix} $$

As small mass of ice is melted, therefore the temperature of the mixture will remain $0^{\circ} C$.

Note To find the temperature of the mixture we must go through the two steps $(Q=m s$ DT $)$ and $(Q=m L)$, we should not directly apply first one.

21. One day in the morning. Ramesh filled up $1 / 3$ bucket of hot water from geyser, to take bath. Remaining $2 / 3$ was to be filled by cold water (at room temperature) to bring mixture to a comfortable temperature. Suddenly Ramesh had to attend to something which would take some times, say 5-10 min before he could take bath. Now, he had two options (i) fill the remaining bucket completely by cold water and then attend to the work, (ii) first attend to the work and fill the remaining bucket just before taking bath. Which option do you think would have kept water warmer? Explain

Show Answer

Thinking Process

We should apply logic in this problem in the context of Newton’s law of cooling which gives a consequence about rate of fall of temperature of a body with respect to the difference of temperature of body and surroundings.

Answer The first option would have kept water warmer because according to Newton’s law of cooling, the rate of loss of heat is directly proportional to the difference of temperature of the body and the surrounding and in the first case the temperature difference is less, so, rate of loss of heat will be less.

Long Answers Type Questions

22. We would like to prepare a scale whose length does not change with temperature. It is proposed to prepare a unit scale of this type whose length remains, say $10 cm$. We can use a bimetallic strip made of brass and iron each of different length whose length (both components) would change in such a way that difference between their length $B$ remain constant. If $\alpha_{\text {iron }}=1.2 \times 10^{-5} / K$ and $\alpha_{\text {brass }}=1.8 \times 10^{-5} / K$, what should we take as length of each strip?

Show Answer

Answer According to question $l_{\text {iron }}-l_{\text {brass }}=10 cm=$ constant at all temperatures

Let $l_0$ be length at temperature $0^{\circ} C$ and $l$ be the length after change in temperature of $\Delta t$.

$$ \begin{aligned} & \text { Now, we can write } \quad l_{\text {iron }}-l_{\text {brass }}=10 cm \text { at all temperatures } \\ & l_{\text {iron }}(1+\alpha_{\text {iron }} \Delta t)-l_{\text {brass }}(1+\alpha_{\text {brass }} \Delta t)=10 cm \\ & l_{\text {ron }} \alpha_{\text {iron }}=l_{\text {brass }} \alpha_{\text {brass }} \\ & \frac{l_{\text {iron }}}{l_{\text {brass }}}=\frac{1.8}{1.2}=\frac{3}{2} \\ & \frac{1}{2} l_{\text {brass }}=10 cm \\ & \Rightarrow \quad l_{\text {brass }}=20 cm \text { and } l_{\text {iron }} 30 cm \end{aligned} $$

23. We would like to make a vessel whose volume does not change with temperature (take a hint from the problem above). We can use brass and iron $(\beta_{\text {vbrass }}=6 \times 10^{-5} / K.$ and $.\beta_{\text {viron }}=3.55 \times 10^{-5} / K)$ to create a volume of 100 cc. How do you think you can achieve this?

Show Answer

Answer In the previous problem the difference in the length was constant. In this problem the difference in volume is constant.

The situation is shown in the diagram.

Let $V_{i o}, V_{b o}$ be the volume of iron and brass vessel at $0^{\circ} C$ $V_{i,}, V_{b}$ be the volume of iron and brass vessel at $\Delta \theta^{\circ} C$,

$\gamma_{i}, \gamma_{b}$ be the coefficient, of volume expansion of iron and brass.

As per question, $\quad V_{i o}-V_{b o}=100 c c=V_{i}-V_{b}$

Now,

Since, $V_{i}-V_{b}=$ constant.

$$ \begin{aligned} V_{i 0}-V_{b o} & =100 c c=V_{i}-V_{b} \\ V_{i} & =V_{i 0}(1+\gamma_{i} \Delta \theta) \\ V_{b} & =V_{b o}(1+\gamma_{b} \Delta \theta) \\ V_{i}-V_{b} & =(V_{i o}-V_{b o})+\Delta \theta(V_{i o} \gamma_{i}-V_{b o} \gamma_{b}) \end{aligned} $$

So,

$$ \begin{aligned} & V_{i o} \gamma_{i}=V_{b o} \gamma_{b} \\ & \frac{V_{i o}}{V_{b o}}=\frac{\gamma_{b}}{\gamma_{i}}=\frac{\frac{3}{2} \beta_{b}}{\frac{3}{2} \beta_{i}}=\frac{\beta_{b}}{\beta_{i}}=\frac{6 \times 10^{-5}}{3.55 \times 10^{-5}}=\frac{6}{3.55} \\ & \frac{V_{i o}}{V_{b o}}=\frac{6}{3.55} \end{aligned} $$

Solving Eqs. (i) and (ii), we get

$$ \begin{aligned} V_{i 0} & =244.9 cc \\ V_{bo} & =144.9 cc \end{aligned} $$

24. Calculate the stress developed inside a tooth cavity filled with copper when hot tea at temperature of $57^{\circ} C$ is drunk. You can take body (tooth) temperature to be $37^{\circ} C$ and $\alpha=1.7 \times 10^{-5} /{ }^{\circ} C$ bulk modulus for copper $=140 \times 10^{9} N / m^{2}$.

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Answer Given, decrease in temperature $(\Delta t)=57-37=20^{\circ} C$

Coefficient of linear expansion $(\alpha)=1.7 \times 10^{-5} /{ }^{\circ} C$

Bulk modulus for copper $(B)=140 \times 10^{9} N / m^{2}$

Coefficient of cubical expansion $(\gamma)=3 \alpha=5.1 \times 10^{-5} /{ }^{\circ} C$

Let initial volume of the cavity be $V$ and its volume increases by $\Delta V$ due to increase in temperature. $\begin{matrix} \therefore & \Delta V=\gamma \vee \Delta t \\ \Rightarrow & \frac{\Delta V}{V}=\gamma \Delta t\end{matrix} $

Thermal stress produced $=B \times$ Volumetric strain

$$ \begin{aligned} & =B \times \frac{\Delta V}{V}=B \times \gamma \Delta t \\ & =140 \times 10^{9} \times(5.1 \times 10^{-5} \times 20) \\ & =1,428 \times 10^{8} N / m^{2} \end{aligned} $$

This is about $10^{3}$ times of atmospheric pressure.

25. A rail track made of steel having length $10 m$ is clamped on a railway line at its two ends (figure). On a summer day due to rise in temperature by $20^{\circ} C$. It is deformed as shown in figure. Find $x$ (displacement of the centre) if $\alpha_{\text {steel }}=1.2 \times 10^{-5} /{ }^{\circ} C$.

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Answer Consider the diagram.

Applying Pythagorus theorem in right angled triangle in figure.

$$ \begin{aligned} (\frac{L+\Delta L}{2})^{2} & =(\frac{L}{2})^{2}+x^{2} \\ x & =\sqrt{(\frac{L+\Delta L}{2})^{2}-(\frac{L}{2})^{2}} \\ & =\frac{1}{2} \sqrt{(L+\Delta L)^{2}-L^{2}} \\ & =\frac{1}{2} \sqrt{(L^{2}+\Delta L^{2}+2 L \Delta L)-L^{2}} \\ & =\frac{1}{2} \sqrt{(\Delta L^{2}+2 L \Delta L)} \end{aligned} $$

As increase in length $\Delta L$ is very small, therefore, neglecting $(\Delta L)^{2}$, we get

But

$$ \begin{aligned} x & =\frac{1}{2} \times \sqrt{2 L \Delta L} \\ \Delta L & =L \alpha \Delta t \end{aligned} $$

Substituting value of $\Delta L$ in Eq. (i) from Eq. (ii)

$$ \begin{aligned} x & =\frac{1}{2} \sqrt{2 L \times L \alpha \Delta t}=\frac{1}{2} L \sqrt{2 \alpha \Delta t} \\ & =\frac{10}{2} \times \sqrt{2 \times 1.2 \times 10^{-5} \times 20} \\ & =5 \times \sqrt{4 \times 1.2 \times 10^{-4}} \\ & =5 \times 2 \times 1.1 \times 10^{-2}=0.11 m=11 cm \end{aligned} $$

Note Here we have assumed $\Delta L$ to be very small so that it can be neglected compared to $L$.

26. A thin rod having length $L_0$ at $0^{\circ} C$ and coefficient of linear expansion $\alpha$ has its two ends maintained at temperatures $\theta_1$ and $\theta_2$, respectively. Find its new length.

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Thinking Process

When temperature of a rod varies linearly, temperature of the middle point of the rod can be taken as mean of temperatures at the two ends.

Answer Consider the diagram

$$ \begin{gathered} \theta_1 \bigcirc \\ \theta=\frac{\theta_1+\theta_2}{2} \end{gathered} $$

Let temperature varies linearly in the rod from its one end to other end. Let $\theta$ be the temperature of the mid-point of the rod. At steady state,

Rate of flow of heat,

$$ (\frac{d Q}{d t})=\frac{K A(\theta_1-\theta)}{(L_0 / 2)}=\frac{K A(\theta-\theta_2)}{(L_0 / 2)} $$

where, $K$ is coefficient of thermal conductivity of the rod.

or $\Rightarrow$

$$ \theta_1-\theta=\theta-\theta_2 $$

or $\Rightarrow$

Using relation,

$$ \theta=\frac{\theta_1+\theta_2}{2} $$

or

$$ \begin{aligned} & L=L_0(1+\alpha \theta) \\ & L=L_0[1+\alpha(\frac{\theta_1+\theta_2}{2})] \end{aligned} $$

27. According to Stefan’s law of radiation, a black body radiates energy $\sigma T^{4}$ from its unit surface area every second where $T$ is the surface temperature of the black body and $\sigma=5.67 \times 10^{-8} W / m^{2} K^{4}$ is known as Stefan’s constant. A nuclear weapon may be thought of as a ball of radius $0.5 m$. When detonated, it reaches temperature of $10^{6} K$ and can be treated as a black body.

(a) Estimate the power it radiates.

(b) If surrounding has water at $30^{\circ} C$, how much water can $10 %$ of the energy produced evaporate in $1 s$ ?

$$ [S_{w}=4186.0 J / kg K \text { and } L_{v}=22.6 \times 10^{5} J / kg] $$

(c) If all this energy $U$ is in the form of radiation, corresponding momentum is $p=U / c$. How much momentum per unit time does it impart on unit area at a distance of $1 km$ ?

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Answer Given, $\sigma=5.67 \times 10^{-8} W / m^{2} kg$

Radius, $=R=0.5 m, T=10^{6} K$ (a) Power radiated by Stefan’s law

$$ \begin{aligned} P & =\sigma A T^{4}=(4 \pi R^{2}) T^{4} \\ & =(5.67 \times 10^{-4} \times 4 \times(3.14) \times(0.5)^{2} \times(10^{6}) 4. \\ & =1.78 \times 10^{17} J / s=1.8 \times 10^{17} J / s \end{aligned} $$

(b) Energy available per second, $U=1.8 \times 10^{17} J / s=18 \times 10^{16} J / s$

Actual energy required to evaporate water $=10 %$ of $1.8 \times 10^{17} J / s$

$$ =1.8 \times 10^{16} J / s $$

Energy used per second to raise the temperature of $m kg$ of water from $30^{\circ} C$ to $100^{\circ} C$ and then into vapour at $100^{\circ} C$

$$ \begin{aligned} & =m s_{w} \Delta \theta+m L_{v}=m \times 4186 \times(100-30)+m \times 22.6 \times 10^{5} \\ & =2.93 \times 10^{5} m+22.6 \times 10^{5} m=25.53 \times 10^{5} m J / s \end{aligned} $$

As per question, $25.53 \times 10^{5} m=1.8 \times 10^{16}$

or

$$ m=\frac{1.8 \times 10^{16}}{25.33 \times 10^{5}}=7.0 \times 10^{9} kg $$

(c) Momentum per unit time,

$$ p=\frac{U}{C}=\frac{U}{C}=\frac{1.8 \times 10^{17}}{3 \times 10^{8}}=6 \times 10^{8} kg-m / s^{2} \quad[\begin{matrix} P=\text { momentum } \\ V=\text { energy } \\ C=\text { velocity of Light } \end{matrix} ] $$

Momentum per unit time per unit

$$ \text { area } p=\frac{p}{4 \pi R^{2}}=\frac{6 \times 10^{8}}{4 \times 3.14 \times(10^{3})^{2}} $$

$\Rightarrow \quad d=47.7 N / m^{2} \quad[4 \pi R^{2}=.$ Surface area $]$



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