Chapter 03 Atoms and Molecules Exercise

Exercises

1. A 0.24g sample of compound of oxygen and boron was found by analysis to contain 0.096g of boron and 0.144g of oxygen. Calculate the percentage composition of the compound by weight.

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Answer

Mass of the compound =0.24g

Mass of boron =0.096g

Mass of oxygen =0.144g

Percentage of boron =Mass of boronMass of compound×100=0.096g0.240g×100=40%

Percentage of oxygen =Mass of oxygenMass of compound×100=0.144g0.240g×100=60%

Alternative method

Percentage of oxygen =100 percentage of boron

=10040=60%

2. When 3.0g of carbon is burnt in 8.00g oxygen, 11.00g of carbon dioxide is produced. What mass of carbon dioxide will be formed when 3.00g of carbon is burnt in 50.00g of oxygen? Which law of chemical combination will govern your answer?

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Answer

First we find the proportion of mass of carbon and oxygen in carbon dioxide.

In CO2,C:O=12:32 or 3:8

In other words, we can say that

12.00g carbon reacts with oxygen =32.00g

3.00g carbon will react with oxygen =32×3=8g

Therefore, 3.00g of carbon will always react with 8.00g of oxygen to form CO2 (11g), even if large amount (50.00g) of oxygen is present. This answer will be governed by ’the law of constant proportions'.

3. What are polyatomic ions? Give examples.

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Answer

The group of atoms which carry a fixed charge (either positive or negative) on them and behave as ions are called polyatomic ions.

Example

(i) Carbonate ion

(ii) Sulphate ion

(iii) Ammonium ion

(iv) Phosphate ion

4. Write the chemical formulae of the following.

(a) Magnesium chloride

(b) Calcium oxide

(c) Copper nitrate

(d) Aluminium chloride

(e) Calcium carbonate.

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Answer

(i) Formula =MgCl2 (Magnesium chloride)

(ii) Formula =CaO (Calcium oxide)

(iii) Formula =Cu(NO3)2 (Copper nitrate)

(iv) Formula =AICl3 (Aluminium Chloride)

(v) Formula =CaCO3 (Calcium carbonate)

5. Give the names of the elements present in the following compounds.

(a) Quick lime

(b) Hydrogen bromide

(c) Baking powder

(d) Potassium sulphate.

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Answer

(a) Quick lime- Calcium oxide - CaO

Elements-Calcium, oxygen.

(b) Hydrogen bromide- HBr

Elements- Hydrogen, bromine.

(c) Baking powder-Sodium hydrogen carbonate - NaHCO3

Elements- Sodium, hydrogen, carbon, oxygen.

(d) Potassium sulphate- K2SO4

Elements- Potassium, sulphur, oxygen.

6. Calculate the molar mass of the following substances.

(a) Ethyne, C2H2

(b) Sulphur molecule, S8

(c) Phosphorus molecule, P4 (Atomic mass of phosphorus = 31)

(d) Hydrochloric acid, HCl

(e) Nitric acid, HNO3

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Answer

(a) Molar mass of C2H2

=(2× Atomic mass of C)+(2× Atomic mass of H)

=(2×12)+(2×1)

=26u

(b) Molar mass of S8

=(8× Atomic mass of S)

=8×32=256u

(c) Molar mass of P4

=4× Atomic mass of P

=4×31=124u

(d) Molar mass of HCl

= Atomic mass of hydrogen + Atomic mass of Cl

=1+35.5=36.5u

(e) Molar mass of HNO3

= Atomic mass of H+ Atomic mass of N+(3× Atomic mass of 0)

=1+14+(3×16)=15+48=63u



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