Matter in Our Surroundings

As we look at our surroundings, we see a large variety of things with different shapes, sizes and textures. Everything in this universe is made up of material which scientists have named “matter”. The air we breathe, the food we eat, stones, clouds, stars, plants and animals, even a small drop of water or a particle of sand - every thing is matter. We can also see as we look around that all the things mentioned above occupy space and have mass. In other words, they have both mass and volume.

Since early times, human beings have been trying to understand their surroundings. Early Indian philosophers classified matter in the form of five basic elements - the “Panch Tatva” - air, earth, fire, sky and water. According to them everything, living or nonliving, was made up of these five basic elements. Ancient Greek philosophers had arrived at a similar classification of matter.

Modern day scientists have evolved two types of classification of matter based on their physical properties and chemical nature.

In this chapter we shall learn about matter based on its physical properties. Chemical aspects of matter will be taken up in subsequent chapters.

1.1 Physical Nature of Matter

1.1.1 MATTER IS MADE UP OF PARTICLES

For a long time, two schools of thought prevailed regarding the nature of matter. One school believed matter to be continuous like a block of wood, whereas, the other thought that matter was made up of particles like sand. Let us perform an activity to decide about the nature of matter - is it continuous or particulate?

Activity 1.1

  • Take a $100 mL$ beaker. Fill half the beaker with water and mark the level of water.

  • Dissolve some salt/ sugar with the help of a glass rod.

  • Observe any change in water level.

  • What do you think has happened to the salt?

  • Where does it disappear?

  • Does the level of water change?

In order to answer these questions we need to use the idea that matter is made up of particles. What was there in the spoon, salt or sugar, has now spread throughout water. This is illustrated in Fig. 1.1.

Fig. 1.1: When we dissolve salt in water, the particles of salt get into the spaces between particles of water.

1.1.2 How SMALL ARE THESE PARTICLES OF MATTER?

Activity 1.2

  • Take $2-3$ crystals of potassium permanganate and dissolve them in $100 mL$ of water.$\cdot$

  • Take out approximately $10 mL$ of this solution and put it into $90 mL$ of clear water.

  • Take out $10 mL$ of this solution and put it into another $90 mL$ of clear water. Keep diluting the solution like this 5 to 8 times.

  • Is the water still coloured?

Fig. 1.2: Estimating how small are the particles of matter. With every dilution, though the colour becomes light, it is still visible.

This experiment shows that just a few crystals of potassium permanganate can colour a large volume of water (about $1000 L$ ). So we conclude that there must be millions of tiny particles in just one crystal of potassium permanganate, which keep on dividing themselves into smaller and smaller particles.

The same activity can be done using $2 ml$ of Dettol instead of potassium permanganate. The smell can be detected even on repeated dilution.

The particles of matter are very small they are small beyond our imagination!!!!

1.2 Characteristics of Particles of Matter

1.2.1 PARTICLES OF MATTER HAVE SPACE BETWEEN THEM

In activities 1.1 and 1.2 we saw that particles of sugar, salt, Dettol, or potassium permanganate got evenly distributed in water. Similarly, when we make tea, coffee or lemonade (nimbu paani), particles of one type of matter get into the spaces between particles of the other. This shows that there is enough space between particles of matter.

1.2.2 PARTICLES OF MATTER ARE CONTINUOUSLY MOVING

Activity 1.3

  • Put an unlit incense stick in a corner of your class. How close do you have to go near it so as to get its smell?

  • Now light the incense stick. What happens? Do you get the smell sitting at a distance?

  • Record your observations.

Activity 1.4

  • Take two glasses/beakers filled with water.

  • Put a drop of blue or red ink slowly and carefully along the sides of the first beaker and honey in the same way in the second beaker.

  • Leave them undisturbed in your house or in a corner of the class.

  • Record your observations.

  • What do you observe immediately after adding the ink drop?

  • What do you observe immediately after adding a drop of honey?

  • How many hours or days does it take for the colour of ink to spread evenly throughout the water?

Activity 1.5

  • Drop a crystal of copper sulphate or potassium permanganate into a glass of hot water and another containing cold water. Do not stir the solution. Allow the crystals to settle at the bottom.

  • What do you observe just above the solid crystal in the glass?

  • What happens as time passes?

  • What does this suggest about the particles of solid and liquid?

  • Does the rate of mixing change with temperature? Why and how?

From the above three activities ($1.3,1.4$ and 1.5), we can conclude the following:

Particles of matter are continuously moving, that is, they possess what we call the kinetic energy. As the temperature rises, particles move faster. So, we can say that with increase in temperature the kinetic energy of the particles also increases.

In the above three activities we observe that particles of matter intermix on their own with each other. They do so by getting into the spaces between the particles. This intermixing of particles of two different types of matter on their own is called diffusion. We also observe that on heating, diffusion becomes faster. Why does this happen?

1.2.3 PARTICLES OF MATTER ATTRACT EACH OTHER

Activity 1.6

  • Play this game in the field- make four groups and form human chains as suggested:

  • The first group should hold each other from the back and lock arms like Idu-Mishmi dancers (Fig. 1.3).

  • The second group should hold hands to form a human chain.

  • The third group should form a chain by touching each other with only their finger tips.

  • Now, the fourth group of students should run around and try to break the three human chains one by one into as many small groups as possible.

  • Which group was the easiest to break? Why?

Fig. 1.3

If we consider each student as a particle of matter, then in which group the particles held each other with the maximum force?

Activity 1.7

  • Take an iron nail, a piece of chalk and a rubber band.

  • Try breaking them by hammering, cutting or stretching.

  • In which of the above three substances do you think the particles are held together with greater force?

Activity 1.8

  • Take some water in a container, try cutting the surface of water with your fingers.

  • Were you able to cut the surface of water?

  • What could be the reason behind the surface of water remaining together?

The above three activities (1.6, 1.7 and 1.8) suggest that particles of matter have force acting between them. This force keeps the particles together. The strength of this force of attraction varies from one kind of matter to another.

Questions

1. Which of the following are matter?

Chair, air, love, smell, hate, almonds, thought, cold, lemon water, smell of perfume.

Show Answer

Answer

Any things which have some weight and occupy space will come under category of matter.

Chair, air, smell, almonds, cold-drink and smell of perfume: Matter

2. Give reasons for the following observation:

The smell of hot sizzling food reaches you several metres away, but to get the smell from cold food you have to go close.

Show Answer

Answer

Evaporation is directly proportional to temperature, means hot food evaporates easily. Diffusion of hot food vapor with air becomes very fast and can reach to a distant place within a very short time.

3. A diver is able to cut through water in a swimming pool. Which property of matter does this observation show?

Show Answer

Answer

The phenomena of cutting the water by the diver show that matter has space between its particles.

4. What are the characteristics of the particles of matter?

Show Answer

Answer

Characteristics of particles of matter are given below:

  1. Particles of matter have space between them.

  2. Particles of matter are continuously moving.

  3. Particles of matter have an attraction force between them.

  4. Particles of matter are very small in size.

1.3 States of Matter

Observe different types of matter around you. What are its different states? We can see that matter around us exists in three different states- solid, liquid and gas. These states of matter arise due to the variation in the characteristics of the particles of matter.

Now, let us study about the properties of these three states of matter in detail.

1.3.1 THE SOLID STATE

Activity 1.9

  • Collect the following articles - a pen, a book, a needle and a piece of wooden stick.

  • Sketch the shape of the above articles in your notebook by moving a pencil around them.

  • Do all these have a definite shape, distinct boundaries and a fixed volume?

  • What happens if they are hammered, pulled or dropped?

  • Are these capable of diffusing into each other?

  • Try compressing them by applying force. Are you able to compress them?

All the above are examples of solids. We can observe that all these have a definite shape, distinct boundaries and fixed volumes, that is, have negligible compressibility. Solids have a tendency to maintain their shape when subjected to outside force. Solids may break under force but it is difficult to change their shape, so they are rigid.

Consider the following:

(a) What about a rubber band, can it change its shape on stretching? Is it a solid?

(b) What about sugar and salt? When kept in different jars these take the shape of the jar. Are they solid?

(c) What about a sponge? It is a solid yet we are able to compress it. Why?

All the above are solids as:

  • A rubber band changes shape under force and regains the same shape when the force is removed. If excessive force is applied, it breaks.
  • The shape of each individual sugar or salt crystal remains fixed, whether we take it in our hand, put it in a plate or in a jar.
  • A sponge has minute holes, in which air is trapped, when we press it, the air is expelled out and we are able to compress it.

1.3.2 The LIQUID STATE

Activity 1.10

  • Collect the following:

(a) water, cooking oil, milk, juice, a cold drink.

(b) containers of different shapes. Put a $50 mL$ mark on these containers using a measuring cylinder from the laboratory.

  • What will happen if these liquids are spilt on the floor?

  • Measure $50 mL$ of any one liquid and transfer it into different containers one by one.

  • Does the volume remain the same?

  • Does the shape of the liquid remain the same?

  • When you pour the liquid from one container into another, does it flow easily?

We observe that liquids have no fixed shape but have a fixed volume. They take up the shape of the container in which they are kept. Liquids flow and change shape, so they are not rigid but can be called fluid.

Refer to activities 1.4 and 1.5 where we saw that solids and liquids can diffuse into liquids. The gases from the atmosphere diffuse and dissolve in water. These gases, especially oxygen and carbon dioxide, are essential for the survival of aquatic animals and plants.

All living creatures need to breathe for survival. The aquatic animals can breathe under water due to the presence of dissolved oxygen in water. Thus, we may conclude that solids, liquids and gases can diffuse into liquids. The rate of diffusion of liquids is higher than that of solids. This is due to the fact that in the liquid state, particles move freely and have greater space between each other as compared to particles in the solid state.

1.3.3 THE GASEOUS STATE

Have you ever observed a balloon seller filling a large number of balloons from a single cylinder of gas? Enquire from him how many balloons is he able to fill from one cylinder. Ask him which gas does he have in the cylinder.

Activity 1.11

  • Take three $100 mL$ syringes and close their nozzles by rubber corks, as shown in Fig.1.4.

  • Remove the pistons from all the syringes.

  • Leaving one syringe untouched, fill water in the second and pieces of chalk in the third.

  • Insert the pistons back into the syringes. You may apply some vaseline on the pistons before inserting them into the syringes for their smooth movement.

  • Now, try to compress the content by pushing the piston in each syringe.

Fig. 1.4

  • What do you observe? In which case was the piston easily pushed in?

  • What do you infer from your observations? We have observed that gases are highly compressible as compared to solids and liquids. The liquefied petroleum gas (LPG) cylinder that we get in our home for cooking or the oxygen supplied to hospitals in cylinders is compressed gas. Compressed natural gas (CNG) is used as fuel these days in vehicles. Due to its high compressibility, large volumes of a gas can be compressed into a small cylinder and transported easily.

We come to know of what is being cooked in the kitchen without even entering there, by the smell that reaches our nostrils. How does this smell reach us? The particles of the aroma of food mix with the particles of air spread from the kitchen, reach us and even farther away. The smell of hot cooked food reaches us in seconds; compare this with the rate of diffusion of solids and liquids. Due to high speed of particles and large space between them, gases show the property of diffusing very fast into other gases.

In the gaseous state, the particles move about randomly at high speed. Due to this random movement, the particles hit each other and also the walls of the container. The pressure exerted by the gas is because of this force exerted by gas particles per unit area on the walls of the container.

Fig. 1.5: $a, b$ and $c$ show the magnified schematic pictures of the three states of matter. The motion of the particles can be seen and compared in the three states of matter.

Questions

1. The mass per unit volume of a substance is called density.

(density = mass/volume). Arrange the following in order of increasing density - air, exhaust from chimneys, honey, water, chalk, cotton and iron.

Show Answer

Answer

We can solve this question by keeping this concept in mind. The correct order of density for gas, liquid and solid are:

Gas $<$ Liquid $<$ Solid. Thus,

Air and exhaust from chimneys are in the gaseous state and have a density that is a lot less than that of water. Hence they will float above the water.

Cotton, despite being a solid, will float on water due to large air pockets between the fibres. Thus, it will come before water in the order.

Honey, chalk, and iron all have densities greater than water and therefore will sink in water.

Cotton is denser than both the gaseous materials in this list on account of it being a solid.

The exhaust from chimneys is denser than air. It has a lot of particulate matter packed in a small volume that increases its density.

Honey is less dense than both chalk and iron since it is a liquid.

​The given substances in the increasing order of their densities can be represented as:

Increasing order of Density

Air $<$ Exhaust from chimney $<$ Cotton $<$ Water $<$ Honey $<$ Chalk $<$ Iron

2. (a) Tabulate the differences in the characterisitcs of states of matter.

(b) Comment upon the following: rigidity, compressibility, fluidity, filling a gas container, shape, kinetic energy and density.

Show Answer

Answer

(a)

Solid: Liquid: Gases :
Solids have a definite volume. Liquids also have a definite volume. Gases do not have a definite volume. Their volume varies with the container in which they are stored or kept.
Solids do not tend to flow. Liquids tend to flow. Gases also tend to flow
Solids are rigid. Liquids are not rigid. Gases are not rigid.
Generally solids have a definite shape with very few exceptions like sponge, rubber band etc. Liquids do not have a definite shape. They take the shape of the container. Gases do not have a definite shape
Solids are generally incompressible with very few exceptions like sponge, rubber band etc. Liquids are almost incompressible. Gases are compressible.

(b)

Rigidity:Property by which an object retains its shape and size is called as rigidity.

Solids are rigid whereas liquids and gases are not.

Compressibility: Compressibility is the property; due to which a substance can be compressed, means its volume can be decreased. Gases are compressible whereas solids and liquids are not.

Fluidity: Flowing tendency of a substance called fluidity. Gases and liquids are fluids, solids are not.

Filling a gas container: a large volume of gas can be filled in a gas container by compressing it under very high pressure. The property of compressibility (of gases) ivey sue full in this case

Shape:The property of having a definite geometry is called shape of a particular

substance. Solids have a definite shape whereas gases and liquids do not have.

Kinetic energy: The energy possessed by a moving object or by the moving molecules of called kinetic energy.

On increasing the temperature, kinetic energy of a substance (or its molecules) also increases. Molecules of gases posses highest kinetic energy.

Density : The mass per unit volume of a substance is called density.

3. Give reasons

(a) A gas fills completely the vessel in which it is kept.

(b) A gas exerts pressure on the walls of the container.

(c) A wooden table should be called a solid.

(d) We can easily move our hand in air but to do the same through a solid block of wood we need a karate expert.

Show Answer

Answer

(a) Force of attraction between the molecules of gases is negligible. So, molecules of gases occupy the maximum space available to them. High kinetic energy possessed by their molecules also helps for the same.

(b) The motion of particles is random and having very high speed in the gaseous state.Due to this random movement, the particles hit each other and also the walls of the container. The pressure exerted by the gas is due to this force exerted by these particles per unit area on the walls of the container.

(c) There is a strong force of attraction between the molecules of wood and the intermolecular space is the least. So, a wooden table has a definite shape and volume and it should be called a solid.

(d) Air molecules are very-very far from each other due to negligible force of attraction working between them. So, our hand gets sufficient space to move in air and we also displace some air molecules by applying force. But a solid block of wood has closely packed molecules so there is no question of the movement of hand through it, in absence of suitable force in proper direction.

4. Liquids generally have lower density as compared to solids. But you must have observed that ice floats on water. Find out why.

Show Answer

Answer

Liquids have lower density than that of solids. Water is also a liquid so it should also have less density than that of solid that is ice.

But the case is not so and the reason for the same is the cage-like structure of ice. i.e., presence of vacant spaces between water $(H_2 O)$ molecules when they linked in ice. The number of these spaces is comparatively less in water. Being more porous than water, ice is lighter than water and floats over the surface of water.

1.4 Can Matter Change its State?

We all know from our observation that water can exist in three states of matter-

  • solid, as ice,

  • liquid, as the familiar water, and

  • gas, as water vapour.

What happens inside the matter during this change of state? What happens to the particles of matter during the change of states? How does this change of state take place? We need answers to these questions, isn’t it?

1.4.1 EFFECT OF CHANGE OF TEMPERATURE

Activity 1.12

  • Take about $150 g$ of ice in a beaker and suspend a laboratory thermometer so that its bulb is in contact with the ice, as in Fig. 1.6.

(a)

(b)

Fig. 1.6: (a) Conversion of ice to water, (b) conversion of water to water vapour

  • Start heating the beaker on a low flame. Note the temperature when the ice starts melting.

  • Note the temperature when all the ice has converted into water.

  • Record your observations for this conversion of solid to liquid state.

  • Now, put a glass rod in the beaker and heat while stirring till the water starts boiling.

  • Keep a careful eye on the thermometer reading till most of the water has vaporised.

  • Record your observations for the conversion of water in the liquid state to the gaseous state.

On increasing the temperature of solids, the kinetic energy of the particles increases. Due to the increase in kinetic energy, the particles start vibrating with greater speed. The energy supplied by heat overcomes the forces of attraction between the particles. The particles leave their fixed positions and start moving more freely. A stage is reached when the solid melts and is converted to a liquid. The minimum temperature at which a solid melts to become a liquid at the atmospheric pressure is called its melting point.

The melting point of a solid is an indication of the strength of the force of attraction between its particles.

The melting point of ice is $273.15 K^{*}$. The process of melting, that is, change of solid state into liquid state is also known as fusion. When a solid melts, its temperature remains the same, so where does the heat energy go?

You must have observed, during the experiment of melting, that the temperature of the system does not change after the melting point is reached, till all the ice melts. This happens even though we continue to heat the beaker, that is, we continue to supply heat. This heat gets used up in changing the state by overcoming the forces of attraction between the particles. As this heat energy is absorbed by ice without showing any rise in temperature, it is considered that it gets hidden into the contents of the beaker and is known as the latent heat. The word latent means hidden. The amount of heat energy that is required to change $1 kg$ of a solid into liquid at atmospheric pressure at its melting point is known as the latent heat of fusion. So, particles in water at $0^{\circ} C(273 K)$ have more energy as compared to particles in ice at the same temperature.

When we supply heat energy to water, particles start moving even faster. At a certain temperature, a point is reached when the particles have enough energy to break free from the forces of attraction of each other. At this temperature the liquid starts changing into gas. The temperature at which a liquid starts boiling at the atmospheric pressure is known as its boiling point. Boiling is a bulk phenomenon. Particles from the bulk of the liquid gain enough energy to change into the vapour state.

For water this temperature is

$$373 \mathrm{~K}\left(100{ }^{\circ} \mathrm{C}=\right. 273+100=373 \mathrm{~K})$$

Can you define the latent heat of vaporisation? Do it in the same way as we have defined the latent heat of fusion. Particles in steam, that is, water vapour at $373 K(100^{\circ} C)$ have more energy than water at the same temperature. This is because particles in steam have absorbed extra energy in the form of latent heat of vaporisation.

So, we infer that the state of matter can be changed into another state by changing the temperature.

We have learnt that substances around us change state from solid to liquid and from liquid to gas on application of heat. But there

Note : Kelvin is the SI unit of temperature, $0^{\circ} C=273.15 K$. For convenience, we take $0^{\circ} C=273 K$ after rounding off the decimal. To change a temperature on the Kelvin scale to the Celsius scale you have to subtract 273 from the given temperature, and to convert a temperature on the Celsius scale to the Kelvin scale you have to add 273 to the given temperature. are some that change directly from solid state to gaseous state and vice versa without changing into the liquid state.

Activity 1.13

  • Take some camphor. Crush it and put it in a china dish.

  • Put an inverted funnel over the china dish.

  • Put a cotton plug on the stem of the funnel, as shown in Fig. 1.7.

Fig. 1.7: Sublimation of camphor

  • Now, heat slowly and observe.

  • What do you infer from the above activity?

A change of state directly from solid to gas without changing into liquid state is called sublimation and the direct change of gas to solid without changing into liquid is called deposition.

1.4.2 EFFECT OF CHANGE OF PRESSURE

We have already learnt that the difference in various states of matter is due to the difference in the distances between the constituent particles. What will happen when we start putting pressure and compress a gas enclosed in a cylinder? Will the particles come closer? Do you think that increasing or decreasing the pressure can change the state of matter?

Fig. 1.8: By applying pressure, particles of matter can be brought close together

Applying pressure and reducing temperature can liquefy gases.

Have you heard of solid carbon dioxide $(CO_2)$ ? It is stored under high pressure. Solid $CO_2$ gets converted directly into gaseous state on decrease of pressure to 1 atmosphere* without coming into liquid state. This is the reason that solid carbon dioxide is also known as dry ice.

Thus, we can say that pressure and temperature determine the state of a substance, whether it will be solid, liquid or gas.

Fig. 1.9: Interconversion of the three states of matter

  • atmosphere (atm) is a unit of measuring pressure exerted by a gas. The unit of pressure is Pascal (Pa): 1 atmosphere $=1.01 \times 10^{5} Pa$. The pressure of air in atmosphere is called atmospheric pressure. The atmospheric pressure at sea level is 1 atmosphere, and is taken as the normal atmospheric pressure.

Questions

1. Convert the following temperature to celsius scale:

a. $300 K$

b. $573 K$

Show Answer

Answer

By the use of given formula, we can convert the Kelvin temperature to Celsius.

$TK-273=t^{\circ} C$

(a) $300 K-273=27^{\circ} C$

(b) $573 K-273=300^{\circ} C$

2. What is the physical state of water at:

a. $250^{\circ} C$

b. $100^{\circ} C$ ?

Show Answer

Answer

As the boiling point of water is $100^{\circ} C$ so

(a) at $250^{\circ} C$, the state of water will be steam or water vapour, i.e., gaseous state.

(b) at $100^{\circ} C$, there will be a transition of liquid state into the gaseous state. So, at this temperature, the state is/may be liquid as well as gaseous.

3. For any substance, why does the temperature remain constant during the change of state?

Show Answer

Answer

During the change of state of a substance, the temperature remains constant. This can be understood with the help of an example. When a solid is heated to its melting point, the temperature first rises and becomes constant when reaches its melting point. Now, on further heating, the heat energy provided to the substance helps to break the attraction force between the solid molecules. This heat is called latent heat. That is why, the temperature does not rise.

4. Suggest a method to liquefy atmospheric gases.

Show Answer

Answer

By applying pressure and reducing the temperature, atmospheric gases can be liquefied

1.5 Evaporation

Do we always need to heat or change pressure for changing the state of matter? Can you quote some examples from everyday life where change of state from liquid to vapour takes place without the liquid reaching the boiling point? Water, when left uncovered, slowly changes into vapour. Wet clothes dry up. What happens to water in the above two examples?

We know that particles of matter are always moving and are never at rest. At a given temperature in any gas, liquid or solid, there are particles with different amounts of kinetic energy. In the case of liquids, a small fraction of particles at the surface, having higher kinetic energy, is able to break away from the forces of attraction of other particles and gets converted into vapour. This phenomenon of change of liquid into vapours at any temperature below its boiling point is called evaporation.

1.5.1 FACTORS AFFECTING EVAPORATION

Let us understand this with an activity.

Activity 1.14

  • Take $5 mL$ of water in a test tube and keep it near a window or under a fan.

  • Take $5 mL$ of water in an open china dish and keep it near a window or under a fan.

  • Take $5 mL$ of water in an open china dish and keep it inside a cupboard or on a shelf in your class.

  • Record the room temperature.

  • Record the time or days taken for the evaporation process in the above cases.

  • Repeat the above three steps of activity on a rainy day and record your observations.

  • What do you infer about the effect of temperature, surface area and wind velocity (speed) on evaporation?

You must have observed that the rate of evaporation increases with-

  • an increase of surface area:

    We know that evaporation is a surface phenomenon. If the surface area is increased, the rate of evaporation increases. For example, while putting clothes for drying up we spread them out.

  • an increase of temperature:

    With the increase of temperature, more number of particles get enough kinetic energy to go into the vapour state.

  • a decrease in humidity:

    Humidity is the amount of water vapour present in air. The air around us cannot hold more than a definite amount of water vapour at a given temperature. If the amount of water in air is already high, the rate of evaporation decreases.

  • an increase in wind speed:

    It is a common observation that clothes dry faster on a windy day. With the increase in wind speed, the particles of water vapour move away with the wind, decreasing the amount of water vapour in the surrounding.

1.5.2 HOW DOES EVAPORATION CAUSE COOLING?

In an open vessel, the liquid keeps on evaporating. The particles of liquid absorb energy from the surrounding to regain the energy lost during evaporation. This absorption of energy from the surroundings make the surroundings cold.

What happens when you pour some acetone (nail polish remover) on your palm? The particles gain energy from your palm or surroundings and evaporate causing the palm to feel cool.

After a hot sunny day, people sprinkle water on the roof or open ground because the large latent heat of vaporisation of water helps to cool the hot surface.

Can you cite some more examples from daily life where we can feel the effect of cooling due to evaporation?

Why should we wear cotton clothes in summer?

During summer, we perspire more because of the mechanism of our body which keeps us cool. We know that during evaporation, the particles at the surface of the liquid gain energy from the surroundings or body surface and change into vapour. The heat energy equal to the latent heat of vaporisation is absorbed from the body leaving the body cool. Cotton, being a good absorber of water helps in absorbing the sweat and exposing it to the atmosphere for easy evaporation. Why do we see water droplets on the outer surface of a glass containing ice-cold water?

Let us take some ice-cold water in a tumbler. Soon we will see water droplets on the outer surface of the tumbler. The water vapour present in air, on coming in contact with the cold glass of water, loses energy and gets converted to liquid state, which we see as water droplets.

Questions

1. Why does a desert cooler cool better on a hot dry day?

Show Answer

Answer

A desert cooler functions on the basis of evaporation. The rate of evaporation increases with increase in temperature and decrease in humidity. As evaporation increases when the day is hot and dry. So, the desert cooler functions to a better extent.

2. How does the water kept in an earthen pot (matka) become cool during summer?

Show Answer

Answer

Large number of tiny pores is present on the surface of the earthen pot (matka). The water stored in the earthen pot (matka) evaporates faster through these pores due to the increased exposed surface area. As the’ process of evaporation causes cooling, the stored water inside the earthen pot (matka) becomes cool.

3. Why does our palm feel cold when we put some acetone or petrol or perfume on it?

Show Answer

Answer

Acetone, petrol, perfume etc., being volatile, evaporate very fast when exposed to larger surfaces. During the process they absorb the required latent heat of vaporization from the palm (if kept on palm). So, the process causes Cooling and the palm feels cool.

4. Why are we able to sip hot tea or milk faster from a saucer rather than a cup?

Show Answer

Answer

A liquid has large surface area in a saucer than in a cup. Thus, it evaporates faster and cools faster in a saucer than in a cup. For this reason we able to sip hot tea or milk faster from a saucer rather than a cup.

5. What type of clothes should we wear in summer?

Show Answer

Answer

We should wear light colored cotton clothes in summer because

  1. Cotton is a good absorber of water/sweat. It provides more surface area for the sweat to evaporate.

  2. Light colours absorb less heat.

So, wearing light coloured cotton clothes helps us feeling cool and comfortable.

What you have learnt

  • Matter is made up of small particles.

  • The matter around us exists in three states-solid, liquid and gas.

  • The forces of attraction between the particles are maximum in solids, intermediate in liquids and minimum in gases.

  • The spaces in between the constituent particles and kinetic energy of the particles are minimum in the case of solids, intermediate in liquids and maximum in gases.

  • The arrangement of particles is most ordered in the case of solids, in the case of liquids layers of particles can slip and slide over each other while for gases, there is no order, particles just move about randomly.

  • The states of matter are inter-convertible. The state of matter can be changed by changing temperature or pressure.

  • Sublimation is the change of solid state directly to gaseous state without going through liquid state.

  • Deposition is the change of gaseous state directly to solid state without going through liquid state.

  • Boiling is a bulk phenomenon. Particles from the bulk (whole) of the liquid change into vapour state.

  • Evaporation is a surface phenomenon. Particles from the surface gain enough energy to overcome the forces of attraction present in the liquid and change into the vapour state.

  • The rate of evaporation depends upon the surface area exposed to the atmosphere, the temperature, the humidity and the wind speed.

  • Evaporation causes cooling.

  • Latent heat of vaporisation is the heat energy required to change $1 kg$ of a liquid to gas at atmospheric pressure at its boiling point.

  • Latent heat of fusion is the amount of heat energy required to change $1 kg$ of solid into liquid at its melting point.

  • Some measurable quantities and their units to remember:

Quantity Unit Symbol
Temperature kelvin $K$
Length metre $m$
Mass kilogram $kg$
Weight newton $N$
Volume cubic metre $m^{3}$
Density kilogram per cubic metre $kg m^{-3}$
Pressure pascal $Pa$

Exercises

1. Convert the following temperatures to the celsius scale.

(a) $293 K$

(b) $470 K$

Show Answer

Answer

In order to covert temperature from Kelvin to Celsius scale, we have to subtract 273 from the given value because $K-273={ }^{\circ} C$

(a) $293 K-273=20^{\circ} C$

(b) $470 K-273=197^{\circ} C$

2. Convert the following temperatures to the kelvin scale.

(a) $25^{\circ} C$

(b) $373^{\circ} C$

Show Answer

Answer

To convert temperature from Celsius to Kelvin scale, add 273 to the given values because ${ }^{\circ} C+273=K$

(a) $25^{\circ} C+273=298 K$

(b) $373^{\circ} C+273=646 K$

3. Give reason for the following observations.

(a) Naphthalene balls disappear with time without leaving any solid.

(b) We can get the smell of perfume sitting several metres away.

Show Answer

Answer

(a) Naphthalene is a substance which directly changes from solid to gas on heating by the process of sublimation. So, the naphthalene balls disappear with time as they sublime due to heat of surroundings.

(b) The smell (aroma) of perfume reaches several meters away due to the fast diffusion of the gaseous perfume particles through the air.

4. Arrange the following substances in increasing order of forces of attraction between the particles - water, sugar, oxygen.

Show Answer

Answer

The forces of attraction are strongest in solids and weakest (or negligible) in case of gases. Sugar is a solid, water is in liquid form and oxygen is a gas so, the order of forces of attraction is oxygen $<$ water $<$ sugar.

5. What is the physical state of water at-

(a) $25^{\circ} C$

(b) $0^{\circ} C$

(c) $100^{\circ} C$ ?

Show Answer

Answer

At zero ${ }^{\circ} C$ temperature water (liquid) get starts to convert into its solid form (ice) and at $100^{\circ} C$ temperature water (liquid) starts to change into water vapours. Between $0^{\circ}$ to $100^{\circ} C$ it remains in liquid state.

Thus,

(a) Liquid state

(b) Solid or/and liquid state (Transition state)

(c) Liquid or/and gaseous state (Transition state)

6. Give two reasons to justify-

(a) water at room temperature is a liquid.

(b) an iron almirah is a solid at room temperature.

Show Answer

Answer

(a) Water is a liquid at room temperature because

It has a tendency to flow.

It takes the shape of the container in which it is filled, but its volume remains the same.

(b) An iron almirah is a solid at room temperature because

Its shape and volume are definite.

It is hard and rigid.

Its density is high.

7. Why is ice at $273 K$ more effective in cooling than water at the same temperature?

Show Answer

Answer

Ice at 273K has less energy than water (although both at the same temperature). Water is having additional latent heat of fusion, hence at $273 K$ ice is more effective cooling than water

8. What produces more severe burns, boiling water or steam?

Show Answer

Answer

Steam causes more severe burns than boiling water. The reason is that it releases the extra amount of heat (latent heat) which it has already taken during vaporization

9. Name A,B,C,D,E and $F$ in the following diagram showing change in its state

Show Answer

Answer

$A=$ Melting or fusion, where solid changes into liquid.

$B=$ Evaporation or vaporization, where liquid changes into gas.

$C=$ Condensation or liquification where gas changes into liquid.

$D=$ Freezing or solidification, where liquid changes into solid.

$E=$ Sublimation, where solid directly changes into gas without coming in liquid state.

$F=$ Sublimation, where gas changes into solid without coming to liquid state.

Group Activity

Prepare a model to demonstrate movement of particles in solids, liquids and gases.

For making this model you will need

  • A transparent jar
  • A big rubber balloon or piece of stretchable rubber sheet
  • A string
  • Few chickpeas or black gram or dry green peas.

How to make?

  • Put the seeds in the jar.

  • Sew the string to the centre of the rubber sheet and put some tape to keep it tied securely.

  • Stretch and tie the rubber sheet on the mouth of the jar.

  • Your model is ready. Now run your fingers up and down the string by first tugging at it slowly and then rapidly.

Fig. 1.10: A model for converting of solid to liquid and liquid to gas.



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