Thermodynamics Question 8

Question 8 - 2024 (30 Jan Shift 2)

Two reactions are given below:

$2 Fe _{(s)}+\frac{3}{2} O _{2(g)} \rightarrow Fe _2 O _{3(s)}, \Delta H^{\circ}=-822 kJ / mol$

$C _{(s)}+\frac{1}{2} O _{2(g)} \rightarrow CO _{(g)}, \Delta H^{\circ}=-110 kJ / mol$

Then enthalpy change for following reaction

$3 C _{(s)}+Fe _2 O _{3(s)} \rightarrow 2 Fe _{(s)}+3 CO _{(g)}$

Show Answer

Answer (492)

Solution

$2 Fe _{(s)}+\frac{3}{2} O _{2(g)} \rightarrow Fe _2 O _{3(s)}, \Delta H^{\circ}=-822 kJ / mol \ldots$ (1)

$C _{(s)}+\frac{1}{2} O _{2(g)} \rightarrow CO _{(g)}, \Delta H^{\circ}=-110 kJ / mol \ldots$ (2)

$3 C _{(s)}+Fe _2 O _{3(s)} \rightarrow 2 Fe _{(s)}+3 CO _{(g)}, \Delta H _3=$ ?

$(3)=3 \times(2)-(1)$

$\Delta H _3=3 \times \Delta H _2-\Delta H _1$

$=3(-110)+822$

$=492 kJ / mole$