General Organic Chemistry Question 23

Question 23 - 2024 (29 Jan Shift 1)

Appearance of blood red colour, on treatment of the sodium fusion extract of an organic compound with $FeSO _4$ in presence of concentrated $H _2 SO _4$ indicates the presence of element/s

(1) $Br$

(2) $N$

(3) $N$ and $S$

(4) $S$

Show Answer

Answer (3)

Solution

Formula: Lead acetate test

$ Fe^{2+} \xrightarrow[\text { Conc. } H _2 SO _4]{H^{+}} Fe^{+3} $

$Fe^{+3} \xrightarrow{-SCN} Fe(SCN) _3($ blood red colour $)$

Appearance of blood red colour indicates presence of both nitrogen and sulphur.