Coordination Compounds Question 17

Question 17 - 2024 (31 Jan Shift 2)

Match List I with List II

LIST - I LIST - II
(Complex ion) (Electronic Configuration)
A. $\left[Cr\left(H _2 O\right) _6\right]^{3+}$ I. $t _2{ }^{2} e _g^{0}$
B. $\left[Fe\left(H _2 O\right) _6\right]^{3+}$ II. $t _2{ }^{3} e _g{ }^{0}$
C. $\left[Ni\left(H _2 O\right) _6\right]^{2+}$ III. $t _2{ }^{3} e^{2}$
D. $\left[V\left(H _2 O\right) _6\right]^{3+}$ IV. $t _2{ }^{6} e^{2}$

Choose the correct answer from the options given below :

(1) A-III, B-II, C-IV, D-I

(2) A-IV, B-I, C-II, D-III

(3) A-IV, B-III, C-I, D-II

(4) A-II, B-III, C-IV, D-I

Show Answer

Answer (4)

Solution

$\left[Cr\left(H _2 O\right) _6\right]^{3+}$ Contains $Cr^{3+}:[Ar] 3 d^{3}: t _2^{3} g _g^{\circ}$

$\left[Fe\left(H _2 O\right) _6\right]^{3+}$ Contains $Fe^{3+}:[Ar] 3 d^{5}: t _2^{3} g _g^{2}$

$\left[Ni\left(H _2 O\right) _6\right]^{2+}$ Contains $Ni^{2+}:[Ar] 3 d^{8}: t _2^{6} g _g^{2}$

$\left[V\left(H _2 O\right) _6\right]^{3+}$ Contains $V^{3+}:[Ar] 3 d^{2}: t _2^{2} e _g^{\circ}$