Coordination Compounds Question 15

Question 15 - 2024 (30 Jan Shift 2)

Number of complexes which show optical isomerism among the following is _________.

cis $-\left[Cr(ox) _2 Cl _2\right]^{3-},\left[Co(en) _3\right]^{3+}$,

cis $-\left[Pt(en) _2 Cl _2\right]^{2+}$, cis $-\left[Co(en) _2 Cl _2\right]^{+}$,

trans $-\left[Pt(en) _2 Cl _2\right]^{2+}$, trans $-\left[Cr(ox) _2 Cl _2\right]^{3-}$

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Answer (4)

Solution

cis $-\left[Cr(ox) _2 Cl _2\right]^{3-} \rightarrow$ can show optical isomerism (no POS & COS)

$\left[Co(en) _3\right]^{3+} \rightarrow$ can show (no POS & COS)

cis $-\left[Pt(en) _2 Cl _2\right]^{2+} \rightarrow$ can show (no POS & COS)

cis $-\left[Co(en) _2 Cl _2\right]^{+} \rightarrow$ can show (no POS & COS)

trans $-\left[Pt(en) _2 Cl _2\right]^{2+} \rightarrow$ can’t show (contains POS & COS)

trans $-\left[Cr(ox) _2 Cl _2\right]^{3-} \rightarrow$ can’t show (contains POS & COS)