Coordination Compounds Question 1

Question 1 - 2024 (01 Feb Shift 1)

Given below are two statements:

Statement (I): A solution of $\left[Ni\left(H _2 O\right) _6\right]^{2+}$ is green in colour.

Statement (II): A solution of $\left[Ni(CN) _4\right]^{2-}$ is colourless.

In the light of the above statements, choose the most appropriate answer from the options given below:

(1) Both Statement I and Statement II are incorrect

(2) Both Statement I and Statement II are correct

(3) Statement I is incorrect but Statement II is correct

(4) Statement I is correct but Statement II is incorrect

Show Answer

Answer (2)

Solution

$\left[Ni\left(H _2 O\right) _6\right]^{+2} \rightarrow$ Green colour solution due to $d-d$ transition.

$\left[Ni(CN) _4\right]^{-2} \rightarrow$ is diamagnetic and it is colourless.