Solid State Question 5

Question 5 - 01 February - Shift 1

Which of the following represents the lattice structure of $A _{0.95} O$ containing $A^{2+}, A^{3+}$ and $O^{2-}$ ions? $\odot A^{2+}$ $\odot A^{3+}$ $\odot O^{2-}$

A.

B.

C.

(1) B and C only

(2) B only

(3) A and B only

(4) A only

Show Answer

Answer: (4)

Solution:

Applying electrical neutrality principle in metal defficiency defect.

$3 A^{2+}$ are replaced by $2 A^{3+}$, thus one vacant site per pair of $A^{3+}$ is created