Redox Reactions Question 7

Question 7 - 30 January - Shift 2

$KMnO_4$ oxidises $I^{-}$in acidic and neutral/faintly alkaline solution, respectively to

(1) $I_2 \& IO_3^{-}$

(2) $IO_3^{-} \& I_2$

(3) $IO_3^{-} \& IO_3^{-}$

(4) $I_2 \& I_2$

Show Answer

Answer: (1)

Solution:

Formula: Redox Reaction

In acidic medium

$2 MnO_4^{-}+10 I^{-}+16 H^{+} \to 2 Mn^{2+}+5 I_2+8 H_2 O$

In neutral/faintly alkaline solution

$2 MnO_4^{-}+I^{-}+H_2 O \to 2 MnO_2+2 OH^{-}+IO_3^{-}$