Aldehydes And Ketones Question 2

Question 2 - 25 January - Shift 1

Given below are two statements : one is labelled as Assertion $A$ and the other is labelled as Reason $R$ :

Assertion $A$ : Acetal/Ketal is stable in basic medium.

Reason $R$ : The high leaving tendency of alkoxide ion gives the stability to acetal/ketal in basic medium.

In the light of the above statements, choose the correct answer from the options given below:

(1) $A$ is true but $R$ is false

(2) $A$ is false but $R$ is true

(3) Both $A$ and $R$ are true and $R$ is the correct explanation of $A$

(4) Both $A$ and $R$ are true but $R$ is NOT the correct explanation of $A$

Show Answer

Answer: (1)

Solution:

Formula: Acetaldehyde

For Assertion :Acetal and ketals are basically ethers hence they must be stable in basic medium but should break down in acidic medium.

Hence assertion is correct.

For reason: Alkoxide ion $(RO^{-})$is not considered a good leaving group hence reason must be false.