Modern Physics 1 Question 38

35. Highly excited states for hydrogen-like atoms (also called Rydberg states) with nuclear charge Ze are defined by their principle quantum number n, where n1. Which of the following statement(s) is (are) true?

(2016 Adv.)

(a) Relative change in the radii of two consecutive orbitals does not depend on Z

(b) Relative change in the radii of two consecutive orbitals varies as 1/n

(c) Relative change in the energy of two consecutive orbitals varies as 1/n3

(d) Relative change in the angular momenta of two consecutive orbitals varies as 1/n

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Solution:

  1. As radius rn2z

Δrr=n+1z2nz2nz2=2n+1n22n1n

Energy, Ez2n2

ΔEE=z2n2z2(n1)2z2(n+1)2=(n+1)2n2n2(n+1)2(n+1)2ΔEE=2n+1n22nn21n

Angular momentum, L=nh2π

ΔLL=(n+1)2πnh2πnh2π=1n1n



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