Transition and InnerTransition Elements - Result Question 96

####23. Consider the following reaction,

(2013 Main) xMnO4+yC2O42+zH+xMn2++2yCO2+z2H2O The values of x,y and z in the reaction are, respectively

(a) 5, 2 and 16

(b) 2,5 and 8

(c) 2,5 and 16

(d) 5,2 and 8

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Solution:

  1. The half equations of the reaction are

MnO4Mn2+ C2O42CO2

The balanced half equations are

MnO4+8H++5eMn2++4H2O C2O422CO2+2e

On equating number of electrons, we get

2MnO4+16H++10e2Mn2++8H2O 5C2O4210CO2+10e

On adding both the equations, we get

2MnO4+5C2O4+16H+2Mn2++2×5CO2+162H2O

Thus x,y and z are 2, 5 and 16 respectively.



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