sblock Elements - Result Question 57

####8. A metal on combustion in excess air forms X.X upon hydrolysis with water yields H2O2 and O2 along with another product. The metal is

(2019 Main, 12 Jan I)

(a) Li

(b) Mg

(c) Rb

(d) Na

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Answer:

Correct Answer: 8. (b)

Solution:

  1. Metal (A) is rubidium (Rb). In excess of air, it forms RbO2(X). X is a superoxide that have O2ion. It is due to the stabilisation of large anion by large cations through lattice energy effects. RbO2(X) gets easily hydrolysed by water to form the hydroxide, H2O2 and O2.

The reaction involved are as follows:

Rb+O2RbO2(X) (superoxide)  2RbO2+2H2O(X)2RbOH+H2O2+O2



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