Qualitative Analysis - Result Question 9

####9. CuSO4 decolourises on addition of KCN, the product is

(2006, 3M)

(a) [Cu(CN)4]2

(b) Cu2+ get reduced to form [Cu(CN)4]3

(c) Cu(CN)2

(d) CuCN

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Answer:

Correct Answer: 9. (b)

Solution:

  1. CuSO4+2KCNCu(CN)2+K2SO4

2Cu(CN)2 Unstable 2Cu(CN)+|CNCN( Cyanogen )CuCN+3KCN3K++[Cu(CN)4]3



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