Qualitative Analysis - Result Question 47

####50. $Fe^{3+} \xrightarrow{SCN^{-} \text {(excess) }}$ Blood red $(A) \xrightarrow{F^{-} \text {(excess) }} \text { Colourless }(B)$

Identify $A$ and $B$.

(i) Write IUPAC name of $A$ and $B$.

(ii) Find out spin only magnetic moment of $B$.

(2005)

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Answer:

Correct Answer: 50. (5.92BM)

Solution:

  1. (i) $Fe^{3+}+3 SCN^{-} \longrightarrow Fe(SCN) _3$ (blood red colouration) Iron (III) thiocyanate

$Fe(SCN) _3+F^{-}$(excess) $\longrightarrow \underset{\substack{\text { (Hexafluoroferrate) } \\ B}}{\left[FeF _6\right]^{3-}}+3 SCN^{-}$

(ii) Magnetic moment $\left(\mu _S\right)=\sqrt{n(n+2)} BM$

$$ =\sqrt{35} BM=5.92 BM $$



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