SATHEE: Qualitative Analysis - Result Question 17

Qualitative Analysis - Result Question 17

####17. In nitroprusside ion the iron and $N O$ exist as $F e$ (II) and $N O^{+}$ rather than $F e$ (III) and NO. These forms can be differentiated by

(1998, 2M)

(a) estimating the concentration of iron

(b) measuring the concentration of $C N$

(d) thermally decomposing the compound

Show Answer

Answer:

Correct Answer: 17. (c)

Solution:

$F e (I I)$ and $F e (I I I)$ will have different values of magnetic moment due to different number of unpaired electrons in their $d$ -orbitals.

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Qualitative Analysis - Result Question 17

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