Extraction of Metals - Result Question 20

####20. In the context of the Hall-Heroult process for the extraction of Al, which of the following statements is false?

(a) CO and CO2 are produced in this process

(2015 Main) (b) Al2O3 is mixed with CaF2 which lowers the melting point of the mixture and brings conductivity

(c) Al3+ is reduced at the cathode to form Al

(d) Na3AlF6 serves as the electrolyte

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Solution:

  1. (a) In Hall-Heroult process for extraction Al, carbon anode is oxidised to CO and CO2.

(b) When Al2O3 is mixed with CaF2, it lowers the melting point of the mixture and brings conductivity.

(c) Al3+ is reduced at cathode to form Al.

(d) Here, Al2O3 is an electrolyte, undergoing the redox process. Na3AlF6 although is an electrolyte but serves as a solvent, not electrolyte.



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