Extraction of Metals - Result Question 14

####14. The electrolytes usually used in the electroplating of gold and silver, respectively, are

(a) [Au(OH)4]and [Ag(OH)2]

(2019 Main, 10 Jan II)

(b) [Au(NH3)2]+and [Ag(CN)2]

(c) [Au(CN)2]and [Ag(CN)2]

(d) [Au(CN)2]and [AgCl2]

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Solution:

  1. Electroplating is a process of coating one metal or metal object with a very thin layer of another metal typically applying a direct electric current.

Electrolytes used in the electroplating of gold and silver are given in the table below:

Process Article to
be plated
out acts as
cathode
Pure metal
block acts an
anode by which
electroplating
will be done
Electrolyte
(aqueous
solution)
(a) Gold
plating
Article Au(s) I
Na[Au(CN)2]
(Sodium
auro-cyanide)
(b) Silver
plating
Article Ag(s) I
Na[Ag(CN)2]
(Sodium argento
cyanide)


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