Extraction of Metals - Result Question 12

####12. The reaction that does not define calcination is

(a) Fe2O3XH2OΔFe2O3+XH2O

(2019 Main, 11 Jan II)

(b) ZnCO3ΔZnO+CO2

(c) CaCO3MgCO3ΔCaO+MgO+2CO2

(d) 2Cu2S+3O2Δ2Cu2O+2SO2

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Solution:

  1. Calcination is one of the pyrometallurgical process, like roasting by which a concentrated ore gets converted into its oxide.

In calcination, a hydrated carbonate or bicarbonate ore or a hydrated ore is heated at lower temperature (compared to roasting) in absence of air to give its oxide as in options (a), (b) and (c). Here, volatile non-metallic oxides like H2O,CO2, are also produced.

Roasting is valid mainly for sulphide ores like option (d), where SO2 gets liberated. In this reaction, calcination cannot be used.



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