Coordination Compounds 2 Question 44

####46. Which of the following is formed when excess of $KCN$ is added to aqueous solution of copper sulphate?

(1996, 1M)

(a) $Cu(CN) _2$

(b) $K _2\left[Cu(CN) _4\right]$

(c) $K\left[Cu(CN) _2\right]$

(d) $K _3\left[Cu(CN) _4\right]$

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Solution:

  1. $Cu^{2+}+CN^{-} \longrightarrow CuCN \downarrow$

$CuCN+3 CN^{-} \longrightarrow\left[Cu(CN) _4\right]^{3-}$



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