SATHEE: Coordination Compounds 2 Question 40

Coordination Compounds 2 Question 40

####42. The compound having tetrahedral geometry is

(a) ${[N i (C N)_{4}]}^{2 -}$

(b) ${[P d (C N)_{4}]}^{2}$

(c) ${[P d C l_{4}]}^{2 -}$

(d) ${[N i C l_{4}]}^{2 -}$

$(2004, 1 M)$

Show Answer

Solution:

${[N i C l_{4}]}^{2 -} : N i^{2 +} (3 d^{8})$ Tetrahedral

In all other complexes, hybridisation at central metal is $d s p^{2}$ and complexes have square planar geometries.

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