Coordination Compounds 1 Question 1

####1. The coordination numbers of Co and Al in [CoCl(en)2]Cl and K3[Al(C2O4)3], respectively, are (en = ethane-1, 2-diamine)

(a) 5 and 3

(b) 3 and 3

(c) 6 and 6

(d) 5 and 6

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Answer:

Correct Answer: 1. (d)

Solution:

  1. Key Idea The total number of ligands to which the metal is directly attached is called coordination number.

The coordination numbers of Co and Al in [Co(Cl)(en)2]Cl and K3[Al(C2O4)3] are 5 and 6 respectively.

In first complex, ’en’ is a didentate ligand and ’ Cl ’ is a unidentate ligand.

[Co(Cl)(en)2]Cl, coordination number =1+2×2=1+45

So, the coordination number is 5 .

For K3[Al(C2O4)3 b ’ C2O42, is a didentate ligand.

Coordination number =3×2=6.

Hence, coordination number is 6 .



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