Aryl Halides and Phenols - Result Question 3

####4. The organic compound that gives following qualitative analysis is

(2019 Main, 9 April I)

Test
Inference

(i) Dil. $HCl$ Insoluble

(ii) $NaOH$ solution

Soluble

(iii) $Br _2$ /water

Decolourisation

(a)

(c)

(b)

(d)

Show Answer

Answer:

Correct Answer: 4. (b)

Solution:

  1. Phenol $(ArOH)$ is insoluble in dil. $HCl$ and readily soluble in $NaOH$ solution. It reacts with $Br _2$ /water to give 2,4 , 6 -tribromophenol. It readily decolourises the yellow colour of $Br _2$ water. Reactions involved are as follows :

(Acidic in nature)



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